New DF Flashcards

1
Q

What’s the molar volume of gases?

A

One mole of ANY gas at room temperature and pressure will take up the same volume. This volume is 24dm3 or 24000cm3.

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2
Q

What is the ideal gas equation?

A

pressure (pascals) x volume (m3) = moles x ideal gas constant (8.31) x temperature (kelvin)

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3
Q

The shapes of simple molecules and ions

A

Determined by the number of electron pairs around the central atom and the repulsion between them. Each electron pair naturally repels each other so that the largest bond angle possible exists between the covalent bonds.

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4
Q

What does a solid line indicate?

A

A bond is in the plane of the paper

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5
Q

What does a wedged line indicate?

A

A bond that comes out of the plane of the paper

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6
Q

What does a dotted line indicate?

A

A bond that goes out of the plane of the paper

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7
Q

What is a single bond?

A

A sigma bond

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8
Q

What does a double bond consist of?

A

A pi and sigma bond

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9
Q

What is enthalpy change measured under?

A

Standard conditions of 100kPa pressure and a specified temperature generally 298K.

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10
Q

What happens to bonds in an endothermic process?

A

Bonds are broken

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11
Q

What happens to bonds in an endothermic process?

A

Bonds are broken

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12
Q

What happens to bonds in an exothermic process?

A

Bonds are made

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13
Q

How to calculate overall enthalpy change?

A

(+ve) + (-ve)

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14
Q

Enthalpy change of reaction

A

The enthalpy change when quantities of substances in standard states react completely under standard conditions

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15
Q

Enthalpy change of formation

A

The enthalpy change when 1 mole of a substance is produced from its elements under standard conditions

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16
Q

Enthalpy change of combustion

A

The enthalpy change when 1 mole of a substance is burned completely in oxygen under standard conditions.

17
Q

Enthalpy change of neutralisation

A

The enthalpy change when solutions of acid and alkali react together under standard conditions to produce 1 mole of water.

18
Q

What is standard conditions?

A

Solution concentrations of 1.00 moldm-3, pressure 100 kPa and a stated temp (generally 298K).

19
Q

What is calorimetry?

A

An experimental method for finding enthalpy change by measuring temperature change over time as a reaction occurs. When data is plotted on a graph, data can be extrapolated to give an accurate value for the change in temperature at the beginning of the reaction.

20
Q

what’s the equation for energy change?

A

Mass (g) x specific heat capacity (J g-1 degrees celsius-1) x temp change ( degrees celsius)

21
Q

What is specific heat capacity?

A

The energy required to raise 1g of the substance by 1K without a change of state.

22
Q

how can I calculate enthalpy change per mole?

A

specific heat capacity/ moles

23
Q

What is Hess’s law?

A

Energy in a reaction must be conserved and it cannot be created or destroyed. The overall enthalpy change for a reaction is the same regardless of the route taken.

24
Q

Enthalpies of formation

A

Arrows point from the central point C as both A and B are formed from the elements C.

25
Q

Enthalpies of combustion

A

Arrows point towards the central product (always H2O and CO2) as both A and B burn to form the products at C.

26
Q

What are catalysts?

A

Lower the activation energy of a reaction by providing an alternative reaction route.

27
Q

What are heterogeneous catalysts?

A

Catalysts in a different phase or state to the species in a reaction.

28
Q

How does a solid heterogeneous catalyst work?

A

Works by adsorbing molecules into an active site on the surface of the catalyst. These active sites increase the proximity of molecules and weaken the covalent bonds in the molecules, allowing reactions to occur more easily. This leads to a faster rate of reaction.

29
Q

Where are heterogeneous catalysts used?

A

In industry to give a surface for the reaction to occur on.

30
Q

What is catalyst poisoning?

A

Impurities in a reaction mixture may bind to heterogeneous catalysts surface and blocks reactants from being adsorbed. Reduces the activity of the catalyst.