Molecular Structure Flashcards

1
Q

What is the empirical formula?

A

The simplest formula for an organic compound - It shows all the elements present in a compound in the simplest ratio. For example, the empirical formula for benzene (C6H6) is just CH.

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2
Q

What is the molecular formula?

A

The molecular formula shows the actual number of atoms of each element in a compound.

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3
Q

How can you work out the molecular formula from an empirical formula?

A

If you know the empirical formula and the relative molecular mass of the compound, the molecular formula can be worked out;
For example, for a compound with the empirical formula CH20 and a relative molecular mass of 60 you would first work out the relative empirical mass (12+2+16=30). As the empirical mass is half of the molecular mass, the molecilar formula must be twice the empirical formula: C2H402.

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4
Q

What is the structural formula?

A

The structural formula shows exactly how the atoms are bonded together and can either be:

  • Full structural formula: All bond between the atoms are displayed.
  • Abbreviates structural formula: The structure is condensed, either just the branches or the whole thing.
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5
Q

What is the skeletal structural formula?

A

The skeletal structural formula uses lines to represent the carbon-carbon backbone. Each line has a carbon at each end of it unless there is another atom attached. The skeletal formula doesn’t show hydrogen atoms that are attached to carbons.

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6
Q

What is wedged line notation?

A

Wedged line notation is a simple way of showing organic molecules with a 3D shape. The plain lines represent bonds that lie in the plane of the paper. The full wedge represents a bond coming out of the paper and the hashed wedge represents a bond behind the paper.

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