Molecular Geometry Flashcards
What does VSEPR stand for
Valence shell electron pair repulsion theory
What is VSEPR
The electron pairs (both shared and unshared) in the outermost energy level try to get as far apart from each other as possible, this determines the shape of the molecule
Linear
2 or 3 atoms connected together in a straight line (180 degrees)
For 3 atoms, the central atom must have no unshared electron pairs
Example of linear
H2
CO2
Bent
3 atoms
The central atom has 1 or 2 unshared electron pairs and thus are more repulsive to the other atoms
If there are 2 pairs then there is more repulsion
Causes bent shape (approximately 104.5 degrees)
Example of bent
H2O
Trigonal planar
4 atoms
Central atom has no unshared electrons
About 120 degrees
Example of rigonal planar
CH2O
Pyramid
4 atoms - but the central atom has an unshared pair
About 107 degrees
Pyramid example
NH3
Tetrahedral
5 atoms
Central atom has no unshared pairs and has 8 valence electrons
About 109.5 degrees
Example of tetrahedral
CH4
Trigonal Bipyramidal
6 atoms
No unshared pairs
About 120 degrees
Example of trigonal bipyramidal
PF5
When can a central atom have an extended octet
Elements in period 3 or higher when bonded with Cl or F