Module 4 - SET B (Part 2) Flashcards
technique for determining the relative positions of atoms within a crystal
X-ray crystallography
orderly, three-dimensional, repeating arrangement of atoms or molecules
crystal
True or False: conditions can be arranged so the intermolecular forces cause the molecules to line up in an organized, repeating manner.
True
provides very precise, high-resolution structural information for molecules in a crystal
x-ray crystallography
used to discover that DNA is a double helix
x-ray crystallography
What is the great advantage of x-ray crystallography?
High-resolution it can provide.
What is the disadvantage of x-ray crystallography?
molecules need to be in crystalline form in order for it to work
true or false: not all molecules can be crystalized so there are other techniques to know their structural information
true
On what principle does the x-ray crystallography operates?
Principle of Diffraction
occurs when the light waves pass through an ordered arrangement of openings (as one finds in a crystal) and interfere with each other on the other side.
diffraction
acts a new starting point for the waves
openings
when waves meet in phase with one another, the peaks from one wave come together with peaks from the other wave, and troughs from one wave come together with the troughs from the other wave
constructive interference
peaks become higher and the troughs become lower
constructive interference
when waves out of phase, a peak and trough come together
destructive interference
waves flatten out and lower the intensity of radiation
destructive interference