Module 4- Core organic chemistry and analysis Flashcards

1
Q

Hydrocarbon

A

A compound consisting of hydrogen and carbon only

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2
Q

Saturated

A

Contain single carbon-carbon bonds only

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3
Q

Unsaturated

A

Contains a C=C double bond

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4
Q

General formula

A

Algebraic formula for a homologous series e.g. CnH2n

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5
Q

Structural formula

A

The minimal detail that shows the arrangement of atoms in a molecule, eg for butane: CH3CH2CH2CH3 or CH3(CH2)2CH3,

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6
Q

Displayed formula

A

All the covalent bonds present in a molecule

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7
Q

Skeletal formula

A

The simplified organic formula, shown by removing hydrogen atoms from alkyl chains, leaving just a carbon skeleton and associated functional Groups

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8
Q

Aliphatic

A

A compound containing carbon and hydrogen joined together in straight chains, branched chains or non-aromatic rings

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9
Q

Alicyclic

A

An aliphatic compound arranged in non-aromatic rings with or without side chains

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10
Q

Aromatic

A

A compound containing a benzene ring

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11
Q

Homologous series

A

Families of organic compounds with the same functional group and same general formula

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12
Q

Functional group

A

An atom or group of atoms which when present in different molecules causes them to have similar chemical properties

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13
Q

Structural isomers

A

Molecules with same molecular formula different structures (or structural formulae)

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14
Q

Chain isomers

A

Compounds with the same molecular formula but different structures of the carbon skeleton

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15
Q

Position isomers

A

Compounds with the same molecular formula but different structures due to different positions of the same functional group on the same carbon skeleton

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16
Q

Functional group isomers

A

Compounds with the same molecular formula but with atoms arranged to give different functional groups

17
Q

Free Radical

A

A reactive species which possess an unpaired electron

18
Q

Homolytic fission

A

Each atom gets one electron from the covalent bond

19
Q

Heterolytic fission

A

One atom gets both electrons

20
Q

Cracking

A

Conversion of large hydrocarbons to smaller molecules of by breakage of C-C bonds

21
Q

Addition reaction

A

A reaction where two molecules react together to produce one

22
Q

Electrophile

A

An electron pair acceptor

23
Q

Primary Haloalkane

A

One carbon attached to the carbon atom adjoining the halogen

24
Q

Secondary Haloalkane

A

Two carbons attached to the carbon atom adjoining the halogen

25
Q

Tertiary Haloalkane

A

Three carbons attached to the carbon atom adjoining the halogen

26
Q

Hydrolysis

A

The splitting of a molecule ( in this case a haloalkane) by a reaction with water

27
Q

Delocalised electrons

A

are shared between more than two atoms.

28
Q

Addition reaction

A

is one in which a reactant is added to an unsaturated molecule to make it saturated.

29
Q

Substitution reaction

A

is on in which an atom or group of atoms is replaced with different atom or group of atoms.

30
Q

Electrophile

A

is an atom (or group of atoms) that is attracted to electron rich centres, where it accepts a pair of electrons to form a new covalent bond.

31
Q

Curly arrow

A

is a symbol used to show the movement of an electron pair.

32
Q

Electronegativity

A

– is a measure of the attraction of a bonded atom for the pair of electrons in its covalent bonds.

33
Q

Stem

A

is the longest carbon chain present in an organic molecule

34
Q

Redox reaction

A

is one where both reduction and oxidation takes place.

35
Q

Reflux

A

is the continual boiling and condensing of a reaction mixture to ensure that the reaction takes place without the contents of the flask boiling dry.

36
Q

Nucleophile

A

is a species which is attracted to electron deficient centres, where it donates an electron pair to form a new covalent bond.

37
Q

Esterification

A

is the reaction between a carboxylic acid and an alcohol to form a ester and water.

38
Q

Hydrolysis

A

is a reaction with water or hydroxide that breaks a chemical compound into two compounds.