Module 3, Section 2 Flashcards
What are the characteristics of an exothermic reaction?
Gives out energy, bond formation. Delta H is negative
What are the characteristics of an endothermic reaction?
Absorbs energy, bond breaking. Delta H is positive
Define standard enthalpy of formation.
The enthalpy change when 1 mole of a substance is formed from it’s elements in their standard states and under standard conditions.
Define standard enthalpy change of combustion.
Enthalpy change when 1 mole of a compound is completely burnt in oxygen, under standard conditions
What is the calculation used when given enthalpies of formation?
Products - Reactants
What is the calculation used when given enthalpies of combustion?
Reactants - Products
Why would delta H be positive?
More energy required when breaking bonds than energy released when forming bonds.
Define activation energy.
Minimum amount of kinetic energy particles need to react
What is the role of a catalyst?
Increases rate of reaction by providing an alternative reaction pathway with a lower activation energy, so more particles have at least the activation energy.
What does a heterogenous catalyst do?
Different physical state to reactants. Reaction happens on surface of catalyst, so an increase in surface area of catalyst, means an increase in the number of molecules reacting at the same time, increasing rate of reaction.
What does a homogenous catalyst do?
Same physical state as reactants. Forms intermediate species, catalyst combines with reactant to make intermediate, which reacts to form products and reform catalyst.
What does le Chatelier’s principle state?
If there’s a change in concentration, pressure or temperature, equilibrium moves to help counteract change
What happens to equilibrium with an increase in temperature?
Equilibrium shifts in endothermic direction to absorb heat
What happens to equilibrium with a decrease in temperature?
Equilibrium shifts in the exothermic direction to release heat
What does a larger value of Kc mean?
Further equilibrium lies to right, more products.