Module 3 (Reactive Chemistry) Flashcards
What are the 5 common ways to observe a chemical change?
A solid is formed (precipitate)
A gas is evolved
Permanent change of colour
Disappearance of solid
Significant change in temperature
What is a physical change? What is an example?
Physical changes are changes affecting the form of a chemical substance, but not its chemical composition. In a physical change, there is no new substance formed and physical changes are easily reversible
An example of this is the boiling of water in which the form of the chemical changes from a liquid to a gaseous state, and no chemical bonds were broken in the process. It is also easy to reverse with little energy
What is a chemical change? What is an example?
a usually irreversible chemical reaction involving the rearrangement of the atoms of one or more substances and a change in their chemical properties or composition, resulting in the formation of at least one new substance.
Another definition could be the breaking down and rearrangement of chemical bonds.
An example of this is the electrolysis of water (Turning water into hydrogen and oxygen molecules), in which chemical bonds are being broken and rearranged. However, it is hard to reverse and requires a lot of energy
List three advantages of using models for chemistry
Any of the three:
Models can communicate observations and ideas to other people
Models help visualise ideas or abstract concepts
Models can be used to make and test predictions
Can be used to help illustrate and explain scientific theories or prove them wrong
List three disadvantages of using models for chemistry
Any of the three:
Don’t include all the details of the objects they represent
Models don’t behave like the things they represent
Accuracy is lost when trying to simplify things into a model
Approximations are used
Why do chemical reactions exist?
They exist because the law of conservation of mass states that matter can be neither created nor destroyed but merely changed from one form to another. In a chemical reaction, mass is conserved through the balancing of both sides so that the number of atoms of each element is conserved
What is a chemical reaction?
a process in which one or more substances, the reactants, are converted to one or more different substances, the products.
How is a chemical reaction formatted?
Reactants on the left side and products on the right side.
Reactants —–> Products
What are the three ways of representing chemical reactions?
Word equations - Chemical names only
Symbolic/ Chemical equations - Chemical Formulae only
Balanced Chemical equations - Number prefixes and states
Need to practice irl
What are the different state symbols?
Solids - ‘S’
Liquid - ‘l’
Gas - ‘g’
Aqueous (dissolved in water - ‘aq’
What is a synthesis/combination reaction? What would the general equation look like?
This reaction is where two reactants produce a single product. This reaction is typically accompanied with a release of energy in the form of heat and/or light
A + B —> AB
What are some (2) examples of synthesis reactions?
Hydrogen + Oxygen —> water
Magnesium + Oxygen —> Magnesium oxide
What are decomposition reactions? What would the general equation look like?
These are basically the opposite of synthesis reactions. Here, the reaction is where a compound is decomposed into two or more other substances. These decomposed substances can be elements or other compounds
AB —> A + B
What is an example of a decomposition reaction
Silver Bromide —> Silver + Bromine
What are the three types of decomposition reactions?
Thermal
Electrical
Light
Where can the energy required for decomposition reactions be derived from?
Heat, light or electricity
What is thermal decomposition?
Thermal decomposition is caused by heat. In this reaction, a chemical reaction occurs when a compound breaks down when heated. It is endomorphic
What is an example of thermal decomposition?
Copper Carbonate + Heat (In an equation, don’t have to mention) —> Carbon dioxide + Copper oxide
What is electrical decomposition?
Electrical decomposition is caused by electricity. In this reaction, an electrical current is passed through a liquid or solution to induce a chemical reaction
What is an example of electrical decomposition?
Electrolysis of water.
Water + electricity (In an equation, don’t have to mention) —> Hydrogen + Oxygen
What is light decomposition?
This type of decomposition is caused by light/photons. In this reaction, light or photons are used to break the reactants to form several products
What is an example of light decomposition?
Silver chloride +light photons (In an equation, don’t have to mention) —> Silver + Chlorine
What is a combustion reaction?
Combustion reactions are reactions in which substances react with oxygen and heat is released. It can often be referred to as an oxidation reaction. Typically a combustion reaction will involve a hydrocarbon. Combustion is a self sustaining chemical reaction that occurs at temperatures above those of the surroundings
What are (3) characteristics of combustion?
Emission of large quantities of heat and light (exothermic)
Formation of new substances
Inability to reverse the reaction
What does combustion of hydrocarbons produce?
Carbon dioxide and water (as long as there is enough oxygen)
What are hydrocarbons?
Compounds which contains mostly the elements carbon and hydrogen
What are the three different types of hydrocarbons?
Alkanes, Alkenes, Alkynes
What are alkanes and their properties? (4)
Alkanes are saturated (meaning that all carbon atoms hold the highest allowed amount of hydrogen atoms). All the bonds between hydrogen and carbon are single bonds. The general formula is C(n) H(2n+2). The suffix is -ane
What are alkenes and their properties? (4)
Alkenes are unsaturated (meaning that all carbon atoms do not hold the highest allowed amount of hydrogen atoms). In alkenes, there is at least one carbon to carbon double bond. The general formula is C(n) H (2n). The suffix is - ene
What are alkynes and their properties? (4)
Alkynes are unsaturated (meaning that all carbon atoms do not hold the highest allowed amount of hydrogen atoms). In alkynes, it consists of at least one carbon to carbon triple bond. The general formula is C(n) H(n). The suffix is -yne
How are alkanes named?
They are named by combining a prefix which describes the number of carbon atoms in the molecule with the root ending ‘ane’
How are alkenes named?
They are named by combining the prefix which describes the number of carbon atoms in the molecule with the root ending ‘ene’
What are the ‘stem names’ for the numbers of carbon atoms in a hydrocarbon chain (1-10)
1 - meth-
2- eth-
3- prop-
4- but-
5- pent-
6- hex-
7- hept-
8- oct-
9- non-
10- dec-
What are complete combustions?
In complete combustions, products are only carbon dioxide and water.
Fuel + oxygen —> carbon dioxide + water (and energy)
What are the 4 steps in writing balanced equations?
- Write the word equation
- Write the chemical formulae
- Balance coefficients in front of each chemical
- Add state symbols
What are incomplete combustions?
Incomplete combustions occur when there is insufficient oxygen to completely react with fuel. Incomplete combustions is inefficient as it does not use the full energy content of the fuel. Here, the amount of fuel consumed is dependent on how much oxygen is available. It produces environmental pollutants such as carbon and carbon dioxide
What are the products of an incomplete combustion (in a reaction)?
In an incomplete combustion the products may include carbon monoxide, carbon dioxide or carbon, and water.
In other words the product of an incomplete combustion can be any of these: carbon, carbon monoxide, carbon dioxide (we pick which one(s) we want to be the product), PLUS HAVE TO INCLUDE water. SO PICK ANY OF THE CARBONS PLUS WATER
I.e. combustion of methane could result in carbon and water; carbon, carbon dioxide and water; carbon, monoxide, carbon dioxide and water; carbon dioxide and water.
What is a precipitate?
A precipitate is an insoluble salt
Why are some substances insoluble?
Some substances will be insoluble if the intermolecular forces between the substance and the water are weaker than those between the solute particles by themselves and the forces between the water molecules themselves
Because of this, ionic lattices stay together, the ions don’t dissociate and the substance remains a solid
What are solutes?
The substancethat dissolves in a solvent to produce a homogeneous mixture.
What are solvents?
A substance that has the ability to dissolve a given solute to form a solution with it
What is a precipitation reaction?
A precipitation reaction is a type of double displacement reaction, where there is the formation of an insoluble substance
What causes a precipitation reaction?
When solutions of two ionic substances are mixed, precipitation occurs if one type of positive ion present is able to combine with another type of negative ion present to form an insoluble substance
What are neutral species equations? Example using sodium chloride and silver nitrate
Neutral Species equations are the normal chemical reaction equations.
I.e. 2NaCl (aq) +Ag(NO3)2 (aq) —> 2NaNO3(aq) +AgCl2 (s)
Where silver chloride is the precipitate
What are complete ionic equations? Example
Complete ionic equations are where each compound is broken up into their disassociated ion equivalents except for the precipitate on the products side (i.e. NaCl would turn into Na^2+ + 2Cl^-)
I.e. 2Na+ + 2Cl- + Ag2+ + 2(NO3)- –> AgCl2 + 2Na+ + 2(NO3)-
What are Net ionic equations? Example using sodium chlroide and silver nitrate
Net Ionic equations are basically complete ionic equations, however, the spectator ions are removed (The ion is unchanged on both sides of a chemical equation)
I.e. (following from the sodium chloride and silver nitrate example)
2Cl- + Ag2+ + —> AgCl2
What is a saturated solution?
A saturated solution is one in which no more of a particular solute can be dissolved in a given quantity of solvent at a specified temperature
What is an unsaturated solution?
Basically the opposite of a saturated solution and is one where there is not as much of a particular solute being dissolved in a given quantity of solvent at a specified temperature
What is the concentration of a solution?
The concentration of a solution is the amount of solute present in a specified amount of solvent or solution
What is an equilibrium?
When a solution becomes saturated, ions still continue to break away from crystals of solid and go into solution, however at the same time an EQUAL number of ion pairs from solution go on to the solid.
This situation is referred to as equilibrium
What symbol indicates equilibrium?
The ‘state rail’ sign indicates equilibrium. The state rail is basically a sign that looks like half an arrow pointing one way, and another half of an arrow pointing the other way
State the solubility rules regarding substances which are SOLUBLE
Eight
All Nitrates
All Acetates
All Sulfates (except calcium, barium, lead, mercury and silver)
All Chlorides, bromides, iodides (Group 7)(except lead, mercury and silver)
All ammonium compounds
Group 1 metals
What are the exceptions to sulfates and chlorides, bromides, iodides being soluble?
Sulfates - Calcium, lead, mercury, silver, barium
Chloride, bromides, iodides - Lead, Mercury, Silver
State the solubility rules regarding substances which are INSOLUBLE
5
All carbonates (except sodium, potassium, ammonium)
All oxides and hydroxides (except sodium, potassium, calcium, magnesium and barium)
All sulfides (except sodium, potassium, magnesium, calcium, barium and ammonium)
All phosphates (except sodium, potassium and ammonium)
What are the products of an acid and reactive metal reaction? Give the layout of the equation
I.e. Magnesium Hydrochloric acid
The products are metal salt typically in the aqueous state (double check) and hydrogen gas
Acid + Metal –> Salt + hydrogen gas
What are the products of an acid and base reaction? Give the layout of the equation
I.e. Sodium hydroxide and Hydrochloric acid
(Known as a neutralisation reaction)
The products are Metal salts and water
Acid+ Metal hydroxide (base) –> Salt + water
What are the products of an acid and a metal carbonate reaction? Give the layout of the equation
I.e. Sulfuric acid and calcium carbonate
The products are metal salts, carbon dioxide gas and water.
Acid+ metal carbonate –> Salt + carbon dioxide gas + water
Note: the products of acid carbonate and acid hydrogen carbonate reactions are the same
How are the ‘salts’ calculated in a chemical reaction?
They are calculated by combining the anions and cations of the first and second reactants which won’t produce any of the products which are guaranteed to have to be the product
I.e. Na + HCl:
H2 would be the guaranteed product, and the rest would combine to give a salt
What are displacement reactions?
Displacement reactions occur when a more reactive metal displaces a less reactive metal and takes its place in a compound (the two switch)
I.e. Cu + 2AgNO3 –> 2Ag + Cu (NO3)2
This occurs because the copper is more reactive than silver
How does reactivity of metals determine if a displacement reaction occurs?
This is because the more reactive the metal, the more likely it is to lose its electrons