module 3 definitions Flashcards
First ionisation energy
of an element is the energy required to remove one electron from each atom in one mole of the gaseous element to form one mole of gaseous 1+ ions.
Disproportionation
is the oxidation and reduction of the same element in a redox reaction.
Activation energy
is the minimum energy required to start a reaction by breaking bods in the reactants.
The enthalpy change of reaction
ΔrHø is the energy change associated with a given reaction.
The enthalpy change of formation
ΔfHø is th eenergy change that takes place when 1 mole of a compound is formed fromits constituent elements in their standard state under standard conditions.
The enthalpy change of combustion
ΔcHø is the energy change that takes place when 1 mole of a substance is completely combsted.
The enthalpy change of neutralisation.
ΔneutHø is the energy change associated with the formation of 1 mole of water from a neuralistion reaction.
Calormetry
is the quantitive study of energy in a chmeical reaction.
Specific heat capactity
is the energy required to raise ther temprature of 1 g of a substance by 1 K.
Avarage bond enthalpy
is the mean energy needed for 1 mole of a given type of gaseous bonds to undergo homolytic fission.
Hess’ law
States that the enthalpy change in a chemical reactionis independant of the route it takes.
An enthalpy cycle
is a pictorial representation showing alternative routes between reactants and products.
The Boltzmjann distribution
is the distribution of energies of molecules at a articular temperature, often shown as a graph.