Module 3 Chapter 7 Flashcards

1
Q

What did Dmitri Mendeleev do

A

He is one of the main chemists credited with the development of the periodic table

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2
Q

How did Mendeleev organise the periodic table

A

He organised elements by atomic mass
He placed elements into groups of which they shared similar chemical properties with
He left gaps where no known elements fitted with the chemical properties of the group

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3
Q

What were the properties of the periodic table in the past

A

60 elements ordered by atomic mass
groups with similar properties
Properties had to fit, elements swapped and gaps left
Assumed incorrect atomic masses and some not discovered
Predicted properties of missing elements using group trends

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4
Q

What are the properties of the periodic table now

A

118 elements
Vertical groups and horizontal periods
Elements arranged in increasing atomic number

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5
Q

How are elements arranged in the periodic table

A

They are arranged in increasing atomic number

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6
Q

What are the properties of groups in the periodic table

A

In each group the elements have atoms with the same number of electrons in the outer shell and similar properties.

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7
Q

What does the period show

A

The number of the period gives the highest energy shell in an elements atom

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8
Q

What is periodicity

A

The repeating trend of properties across the period

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9
Q

What determines the chemistry of an element

A

A lot of the chemistry is determined by electron configuration, particularly the highest energy outer shell.

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10
Q

What are some trends in periodicity

A

Ionisation energy
Structure
Melting points

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11
Q

What is the trend of the highest energy sub shell where the electrons are held as you go across period 2, 3 and 4

A

Across period 2: 2S —> 2P
Across period 3: 3S —> 3p
Across period 4: 4S —> 3D —> 4P

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12
Q

How many groups are in the periodic table

A

There are 18 groups in the periodic table

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13
Q

What is Group 15 called

A

The Pnictogens

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14
Q

What is group 16 called

A

The Chalogens

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15
Q

What is group 1 called

A

The alkali metals

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16
Q

What is group 3 called

A

The alkaline earth metals

17
Q

What are groups 3-12 called

A

The transition metals

18
Q

what is group 17 called

A

The halogens

19
Q

What is group 18 called

A

The noble gases

20
Q

What is the trend of reactivity as you go down Group 1

A

The reactivity increases as you go down the group

21
Q

Why does the reactivity increase as you go down group one

A

The atomic radius increases, so the force of attraction between the nucleus and electrons in the outer shell is weaker, therefore it looses its electrons to form ions more easily and is therefore more reactive.

22
Q

What is ionisation energy

A

It measures how easily and atom can lose electrons to form positive ions

23
Q

What is first ionisation energy

A

The energy required to remove one electron from each atom in one mole of gaseous atoms of an element to form one mole of gaseous 1+ ions.

24
Q

What are the three factors affecting first ionisation energy

A
  1. Atomic radius
  2. Nuclear charge
  3. Electron shielding
25
Q

Where is the first electron lost in an atom

A

It is lost from the highest energy level and therefore experiences the least attraction from the nucleus.

26
Q

How does atomic radius affect ionisation energy

A

The greater the distance from the nucleus and outer shell the less nuclear attraction from the nucleus. As the force of attraction decreases with increasing distance.

27
Q

How does nuclear charge affect first ionisation energy

A

The more protons there aer in the nucleus of an atom the greater the attraction between the nucleus and outer electrons.

28
Q

How does electron shielding affect ionisation energy

A

They are negatively charged, the inner-shell electrons repel the outer shell electrons. This repulsion leads to a shielding effect reducing the attraction.

29
Q

Which of the three factors has the greatest affect on ionisation energy

A

Atomic radius

30
Q

What is second ionisation energy

A

The energy required to remove one electron from each ion in one mole of gaseous 1+ ions of an element to form one mole of gaseous 2+ ions.

31
Q

Why is the second ionisation energy always greater than the first

A

Because more energy is required to remove the second electron as the nuclear charge increases as there are less electrons attracted to the same number of protons.