Module 2 Flashcards

Thermodynamic Properties of a pure substance

1
Q

What are the single phase regions?

A

Solid, (compressed) Liquid, (super-heated) Vapor

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2
Q

A pure substance may exist in what three phases?

A

Solid, liquid and vapor

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3
Q

what are the 3 most common phase diagrams used in thermodynamics?

A

P-v, P-T & T-v diagrams

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4
Q

What are two phase regions? And how are they distinguished?

A

Two phase regions are shown as lines separating different phases.
Vaporization line: separates the liquid and vapor phases.
Fusion Line: Separates the solid and liquid phases.
Sublimation line: Separates the solid and vapor phases.

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5
Q

What is meant by Triple point?

A

This is the point at which the three phases coexist in equilibrium.

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6
Q

What is the temperature on the vaporization line called? and what happens at this temperature?

A

Saturation temperature is the temperature at which evaporation or condensation takes place at a given saturation pressure. Remember, for each saturation temp there is a saturation pressure.

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7
Q

What is meant by Critical Point?

A

This is the point where saturated liquid and saturated vapor lines meet. Pressure and temperature at this point are called critical pressure and critical temperature.

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8
Q

What is the state called when P>Pc? What happens when this is the case?

A

Super-critical state. Liquid and vapor cannot coexist in equilibrium.

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9
Q

What is the state called when P

A

Sub-critical state. Liquid and vapor can coexist in equilibrium.

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10
Q

What name is given to the liquid state of a substance? why?

A

Compressed liquid or super-cooled liquid, this is because at a given pressure, P>Psat and T

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11
Q

What name is given to the vapor state of a substance? why?

A

Super-heated vapor. this is because at a given Pressure, T>Tsat.

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12
Q

What is unique about the two phase region?

A

T=Tsat and P=Psat

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13
Q

How many independent properties do you need from this list T,P,x,v,u,h,s to determine the state?

A

Two!!!

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14
Q

If P>Psat or T>Tsat what is the phase?

A

Compressed Liquid

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15
Q

If P=Psat or T=Tsat what is the state?

A

Two-phase Mixture

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16
Q

If PTsat what is the state?

A

Super heated vapor

17
Q

If T or P and x are given then what is said about the state?

A

it is a two phase mixture if T=Tsat and P=Psat. and find vuhs for the mixture.

18
Q

If T or P and v or u,h,s are given what do you look for in the tables?

A

the values of vf, v, vg, uf, u, ug, sf, s, sg, hf, h, hg

19
Q

If v

A

Compressed liquid

20
Q

If vf

A

Two phase Mixture

21
Q

If v>vg or u>ug, h>hg, s>sg what is the state?

A

Super-heated Vapor

22
Q

What is to be assumed if the compressed liquid table is not available?

A

v≈vf, u≈uf, h≈hf, s≈sf

23
Q

What does “x” represent? and how is it calculated?

A

The vapor quality!!! x=mg/mmix . mg is mass of vapor, mmix is total mass of mixture.

24
Q

What does the fusion line represent?

A

it separates the solid and liquid phases

25
Q

What does the sublimation line represent?

A

it separates the solid and vapor phases

26
Q

What can the three phases be illustrated in?

A

a pressure-specific volume-temperature surface. PvT

27
Q

What does the Vaporization line represent?

A

separates the liquid and vapor phases.

28
Q

What does Entropy quantify?

A

it quantifies how orderly the energy of a system is distributed among its molecules.

29
Q

What id the work called when it is associated with flowing fluid?

A

Flow work.

30
Q

What is the zeroth law of thermodynamics?

A

If two bodies are in thermal equilibrium with a third, the three bodies must be in equilibrium with each other