Module 2 Flashcards
Covalent compounds
Share electrons, usually have low boiling/melting points
Non-polar covalent bonds
Electrons are shared equally
Polar covalent bonds
Electrons are shared unequally, gives rise to dipole moments
Dipole moment
Occurs when there’s a separation of charges within a bond, arises from differences in electronegativity
How are bond order and length related?
Inversely. When bond order increases (triple bond vs single bond), bond length decreases
How are bond length and bond energy related?
Inversely. As bond length decreases, bond energy increases.
How are bond order and bond energy related?
Proportionally. As bond length increases, bond energy also increases
Electron affinity
The amount of energy released when an electron attaches to a neutral form atom or molecule, while in a gaseous state. A physical quality, measures the attraction between the incoming electron and the nucleus
Electronegativity
Describes how tightly an atom attracts electrons in a bond. It’s a dimensionless adjective, a quantity that is calculated, not measured.
How to calculate formal charge
of valence electrons - # of lone pair electrons - 1/2 of the total number of bonding electrons
The 1/2 bonding electrons is equal to the number of bond lines drawn on the lewis structure attached to the atom in questions
To double check calculations, the sum of the formal charges for all the atoms in a molecule should be zero or equal to the charge of the ion if applicable
Definition of formal charge
The hypothetical charge an atom would have if we could redistribute the electrons in the bonds evenly between the atoms. It’s not actually the charge of the atom in the molecule, it’s just a bookkeeping total
Definition of solubility
The quantitative extent to which a substance may be dissolved in water
When will a substance precipitate?
When its concentration in a given solution exceeds the substance’s solubility
What is an oxyacid?
An acid molecule containing hydrogen, oxygen and one other element (usually a nonmetal)
Definition of a solution
A homogenous mixture consisting of a solute and a solvent
Definition of a solute
The substance in a solution that dissolves
Definition of a solvent
The substance into which things are dissolved in a solution
Concentration
The amount of solute per amount of solvent
What are electrolytes?
Molecules that dissolve their charges into water and conduct electricity. Any and all acidic and basic molecules are electrolytes
What makes something a non-elecrolyte?
Not being able to ionize in solution, therefore not conducting electricity. Includes polar covalent non-ionizing molecules, sugars, ethanol, organics, etc..
Arrhenius acid
Generates H+ in aqueous solutions
Arrhenius bases
Generates OH- in aqueous solutions
Bronstead-Lowry acids
Molecule is a H+ donor
Bronstead-Lowry bases
Molecule is an H+ acceptor
What drives redox reactions?
Reduction in potential energy
How do you recognize an acid/base reaction?
Water and a salt are formed from an acid and a base
Criteria for an ideal gas
Infinitely small volume and perfectly elastic collisions
List of memorized strong acids
HCl, HBr, HI, H2SO4, HClO4, HNO3
Strong bases
All alkali metal hydroxides (NaOH, KOH, etc) and alkaline earth metal hydroxides (Mg(OH)2, etc)
2 ligands, 2 electron groups
Linear
2 ligands, 3 electron groups
Bent
2 ligands, 4 electron groups
Bent
3 ligands, 3 electron groups
Trigonal planar
3 ligands, 4 electron groups
Trigonal pyramidal
4 ligands, 4 electron groups
tetrahedral
Which bond angle is greater: the ones between the ligands of a trigonal pyramidal molecule, or the ones between the ligands of a tetrahedral ligand?
Tetrahedral is 109.5
Trigonal planar is <109.5
Bond angles between the ligands of a tetrahedral molecule
109.5
Bond angles between the ligands of a trigonal pyramidal molecule
< 109.5
Bond angles between the ligands of a trigonal planar molecule
120
Bond angles between the ligands of a linear molecule
180
Bond angles between the ligands of a bent molecule (linear with a bonus electron group)
< 180
Bond angles between the ligands of an extra ment molecule (linear with two bonus electron groups)
«_space;180
Steps to balancing redox rxns
- Split into half rxns
- Balance everything that’s not O or H
- Add water to balance O
- Add H+ to balance H
- Add electrons to balance charge
- Combine
- Add one hydroxide for every H+ on both sides
- Combine H+ with OH- to form water
- Cancel anything remaining and combine