Lab Quiz #2 Flashcards
Absorbance (A)
-log(P/P0) = -log(T) = (molar absorptivity)(path length)(concentration)
Concentration (c)
= (absorbtivity)(cm or unit of length) / (absorbance) = ab/A
Flow of light through a spectrophotometer
Light source –> lens –> sample cell –> slit –> diffraction grating –> diode array detector
Cuvette
Sample container for spectroscopic measurements
Absorptivity
A proportionality constant, constant characteristic for a given absorbing species at a specific wavelength
Beer’s Law
Relates absorbance to concentration
A = (molar absorptivity)(path length)(concentration)
A substance is shown to absorb wavelengths in the 400-500 nm range and the 650-700 nm range. What color is the substance?
Substance must transmit wavelengths in the 500-650 nm range, so it must be green.
What temperature is a bunsen burner if its flame is luminous and yellow?
Cool
What temperature is a bunsen burner in its pale blue violet outer region?
Moderately hot
What temperature is a bunsen burner in its dark blue inner cone?
Extremely hot
Bowl shaped porcelainware with a lid
Crucible
Bowl shaped porcelainware with a handle and a pouring lip
Casserole
Do solid crystalline materials have the exact ratio of atoms predicted by their ideal chemical formulas?
No. The ratio may vary due to defects in the crystal structure
Nonstoichiometric solids
Solids whose crystal structures have a ratio of atoms different from the one predicted by their ideal chemical formula
What are nonstoichiometric solids also known as?
Berthollides