Modern Physics Flashcards
Rutherford Nuclear Model
Dense positive nucleus surrounded by a swarm of negatively charged electeons
Determined through Rutherford gold foil experiment in which alpha particles were deflected by nucleus
Particle-like Nature of Light Revealed by who?
The particle-like nature of light was revealed and studied through the work of Max Planck in 1900, and later Albert Einstein (who won the 1921 Nobel prize for work in this area)
Quanta
Electromagnetic radiation is emitted and absorbed by matter as though it existed in individual bundles called quanta
- Discrete packet of energy
Photon
A quantum of electromagnetic energy is known as a photon
- Light behaves like a stream of photons, which is illustrated by the photoelectric effect
Photoelectrons
When a piece of metal is illuminated by electromagnetic radiation (visible light ultraviolet light, or X-rays), the energy absorbed by electrons near the surface of the metal can liberate them from their bound state, and these electrons can fly off
- The released electrons are known as photoelectrons
Wave-only Theory of Light Prediction of photoelectrons
- There would be siginifcant time delay betwen the moment of illumination and the ejection of photoelectrons
- Increasing the intensity of light would cause the elctrons to leave the metal surface with greater kinetic energy
- Photoelectrons would be emitted regardless of the frequency of the incident energy, as long as the intensity was high enough
None of these predictions was observed, something was wrong with the wave-only theory of light
Inaccuracies of Wave-only Theory of Light Predictions
- Photoelectrons were ejected within just a few billionths of a second after illumination
- Increasing the intensity of light did not cause photoelectrons to leave the metal surface with greater kinetic energy; although more electrons were ejected as the intensity was increased, there was a certain threshold frequency, f0
- If light of frequency lower than f0 were used to illuminate the metal surface, no photoelectrons were ejected regardless of how intense the incident radiation was
Energy of Photon
E= hf
- h= Planck’s constant (about 6.63 x 10-34 J•s)
Photoelectric Effect Formula
Kmax= hf - Ø
- A certain amount of energy had to be imparted to an electron on the metal surface in order to liberate it
- This is known as the metal’s work function, Ø
- If an electron absorbed a photon whose energy E was greater than Ø, it would leave the metal with a maximum kinetic energy equal to E - Ø or hf - Ø
- This process could occur very quickly, which accounts for the rapidity with which photoelectrons are produced after illumination
- Increasing the intensity of the incident energy means bombardment with more photons and results in the ejection of more photoelectrons
- But since the energy of each incident photon is fixed by the equation E= hf, the value of Kmax will still be E - Ø
- This is known as the metal’s work function, Ø
Threshold Frequency
E= hf
- Ø= hf
- Amount of needed energy to be imparted to an electron on the metal surface in order to liberate it
- Ø/h= f, threshold frequency
- If the incident energy had a frequency that was less than Ø/h, the incident photons would each have an energy that was less than Ø; this would not be enough energy to liberate photons
- Blasting the metal surface with more photons (that is increasing the intensity of the incident beam) would also do nothing as none of these photons would have enough energy to eject electrons, so whether there were one or million wouldn’t make a difference
- This accounts for a threshold frequency, Ø/h
- Blasting the metal surface with more photons (that is increasing the intensity of the incident beam) would also do nothing as none of these photons would have enough energy to eject electrons, so whether there were one or million wouldn’t make a difference
- If the incident energy had a frequency that was less than Ø/h, the incident photons would each have an energy that was less than Ø; this would not be enough energy to liberate photons
Formula Relating Wavelength, Speed, and Frequency
c= λf
Electronvolt
- The SI unit for energy is the joule, but it is too large to be used in instances relating to photoelectrons/ electrons
- The electronvolt (eV) is equal to the energy gained (or lost) by an electron acclerated through a potential difference of one volt
- Using the equation ΔUE= qΔV
- 1 eV= (1 e)(1 V)= (1.6 x 10-19 C) (1 V)= 1.6 x 10-19 J
- Using the equation ΔUE= qΔV
- The electronvolt (eV) is equal to the energy gained (or lost) by an electron acclerated through a potential difference of one volt
- In terms of electronvolts, the value of Planck’s constant is 4.14 x 10-15 eV•s
Atomic Spectra
When atoms are excited they emit light of certain wavelengths which correspond to different colors. The emitted light can be observed as a series of colored lines with dark spaces in between; this series of colored lines is called a line or atomic spectra. Each element produces a unique set of spectral lines
The Bohr Model of the Atom
- According to Bohr model, electron orbits the nucleus at certain discrete radii (energy levels)
- If electron aborbs photon or certain amount of energy it is excited to a higher orbit, which is known as its excited state
- After spending a short time in its excited state, it returns to a lower orbit, emitting a photon in the process
- If electron aborbs photon or certain amount of energy it is excited to a higher orbit, which is known as its excited state
- Since each energy level has a specific radius (and corresponding specific energy), the photons emitted in each jump also have specific energy and wavelengths
- The electron’s energy levels are quantized
Formula for Energy of Energy Level
The energy levels within the hydrogen atom are given by the formula: En= 1/n2(-13.6 eV)
- For other one-electron atoms, doubly-ionized lithium, the energy levels are:
- En= Z2/n2 (-13.6 eV)
- Where Z is the number of protons in the atom’s nucleus
- En= Z2/n2 (-13.6 eV)
- When an excited electron drops from energy level n= j to a lower one, n= i, the transition causes a photon of energy to be emitted, and the energy of the photon is the difference between the two energy levels
- Eemitted photon= |ΔE|= Ej - Ei
Wave-Particle Duality
Light and other electromagnetic waves exhibit wave-like characteristics through interference and diffraction
- As seen in the photoelectric effect, light also behaves as if its energy were granular, composed of particles
- Wave-particle duality: Electromagnetic radiation propagates like a wave but exchanges energy like a partcile
de Broglie Wavelength
λ= h/p
- A particle of mass m and speed v, with linear momentum p- mv has an associated wavelength
- Particles in motion can display wave characteristics and behave as if they had a wavelength
- Since the value of h is so small, ordinary macroscopic objects do not display wavelike behavior, however, with subatomic particles, the wave nature is clearly evident
- Particles in motion can display wave characteristics and behave as if they had a wavelength
Nucleons
- The nucleus of the atom is composed of particles called protons and neutrons, which are collectively called nucleons
- The total number of nucleons, atomic number + nucleus number= the mass number (or nucleon number)
- Nuclide: term for a nucleus with specific numbers of protons and neutrons
The Nuclear Force
The strong nuclear force, is a fundamental force which binds together neutrons and protons to form nuclei
- The coloumb force can be expressed by a smiple mathematical formula
- The nuclear force is much more complicated; no simple formula can be written for the strength of the nuclear force
Binding Energy
The difference between the mass of any bound nucleus and the sum of the mass of its constituent nucleons is called the mass defect Δm
Δm= (mproton + mneutron) - mnucleus
- The missing mass is converted to energy when the nucleus is formed
- The energy represent the amount of energy needed to break the nucleus into separate protons and neutrons, since this indicates how strongly a nucleus is bound, it is called the binding energy of the nucleus
Atomic Mass Unit
- Mass of proton: 1.6726 x 10-27 kg
- Mass of neutron: 1.6749 x 10-27 kg
- Because the masses are so tiny, a much smaller mass unit is used
- The atomic mass unit amu, is defined as 1/12 the mass of a carbon-12 atom
- The conversion between kg and u is 1 u-= 1.6605 x 10-27 kg
- Proton mass = 1.00728 u
- Neutron mass= 1.00867 u
- Because the masses are so tiny, a much smaller mass unit is used
Deuterium
Deterium is an isotope of hydrogen that contains 1 proton and 1 neutron
- Deuteron is the nucleus of deuterium
- The mass of deuteron is 2.01356 u