modern atomic theory Flashcards
quantum mechanical model
what are three ways in which the quantum model improves on Bohr’s model?
- it can distinguish between energy differences within an energy level
- it better reflects the uncertainty of electrons’ position
- it can be explained entirely mathematically by the wave equation
thomson
discovered electrons (through the cathode ray experiment)
rutherford
discovered the nucleus (through the gold foil experiment)
bohr
discovered energy levels (best evidence line emission spectra)
bohr/shroedinger
introduced quantum (cloud) model
aufbau principle
when filling an atom with electrons, you always start with the lowest energy orbitals and gradually move to higher energy levels (“building up”)
hund’s rule
fill orbitals singly first, then start pairing
pauli exclusion principle
(1) no more than two electrons can occupy the same orbital
(2) two electrons in the same orbital must have opposite spins
how do excited states work?
electrons gain energy to move to higher position in the Aufbau sequence and release energy when they return to ground state
how are noble gas electron configurations formed?
positive ions lose electrons and negative ions gain electrons
filling capacity of s sublevel
2 electons
filling capacity of p sublevel
6 electrons
filling capacity of d sublevel
10 electrons
filling capacity of f sublevel
14 electrons
how many orbitals in s sublevel?
1