Mod. 6 Flashcards
What did Lovoiser suggest?
- An acid contains oxygen
- Non-metal oxides react with water to form acidic solutions
What did Darvy suggest?
- Acids contain hydrogen
- Metal oxides = bases
What was Arrhenius’s proposal?
Acids produce H+ ions in water and bases produce OH- ions in water, in aqueous solutions
- Arrhenius explained neutralisation
What were the limitations of Arrhenius’s proposal?
- Could not explain why certain compounds do not contain hydroxide ions, despite displaying basic properties, e.g. 2HCI + CaCO3 → CaCl2 + H2O + CO2 [calcium carbonate is basic but doenst contain OH]
-Could not explain acid-base reaction that do not occur in aqueous solutions, e.g.
NH3(g)+ HCI(g)→ NH4Cl(s)
What did Bronsted Lowry’s proposal?
- acid donates H+ protons
- bases accept H+ protons
- acids have high concentrations of H+
- bases have lower concentrations of H+
What were the limitations of B-L theory?
- Doesn’t explain the acidity of acidic oxides ( SO2)/ basicity of basic oxides ( MgO)
- Doesn’t explain reaction between acidic and basic oxides that don’t involve proton transfer, e.g. SO3(g)+ CaO(s)→ CaSO4(s)
What’s an inorganic acid?
a substance with an ion attached to 1 or more hydrogen
What’s an inorganic base?
a substance that releases OH- in solutions
What’s the equation for acid-carbonate reactions?
carbonate + acid –> salt + carbon dioxide + water
Provide an example of an acid-carbonate reaction.
2HI(aq) + Na2CO3 –> NaCl ( aq) + CO2( g) + H20 (l)
What’s the equation for acid-metal reactions?
acid + metal hydroxide –> salt + water
Provide an example of an acid-metal reaction.
Na(s) + HCI( aq) –> NaCl (aq) + 1/2 H20(l)
What does neutralisation mean?
when the concentration of hydronium and hydroxide ions becomes equal
What’s the equation for a neutralisation reaction?
acid + base → salt + water
Provide an example of a neutralisation reaction.
NaOH(aq) + HNO3(aq) –>Na NO3(aq)+H2O(l)
Name 3 strong acids
HCI, H2SO4, HNO3
Name 3 weak base.
CH3COOH, H2CO3, H3PO4
Name 3 strong bases.
NaOH, KOH, H3PO4
Name 3 weak bases
NH3, C5H5N, CH3NH2
Define hydrolysis.
the reaction of a salt with water that results in a pH change
Explain the hydrolysis of acidic salts.
acidic salts contain conjugate acids of weak bases which hydrolise to produce acidic solutions.
Explain the hydrolysis of basic salts
basic salts contain conjugate bases of weak acids which hydrolise to produce an alkaline
Explain the hydrolysis of neutral salts
typically formed from the neutralisation between strong acids and strong bases ( do not hydrolyse)
What happens to the volume and concentration when diluted?
the volume increases and the concentration decreases