mod 5 IQ2 Flashcards

1
Q

What does Le Chatelier’s principle state?

A

When a system in equilibrium is subjected to a change in concentration, temperature, external pressure, or some other factor which upsets the equilibrium, the system reacts in such a way as to counteract that change and achieve a new equilibrium state

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2
Q

What happens to a system at equilibrium if you increase pressure

A

the equilibrium will shift to the side with fewer gaseous moles

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3
Q

What happens to a system at equilibrium if you decrease pressure?

A

equilibrium will shift to the side with more gas particles

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4
Q

What happens if you increase the concentration of the reactants?

A

forward rate of reaction increases and equilibrium shifts to the right

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5
Q

What happens to a system at equilibrium if you decrease the concentration of reactant

A

reverse rate of reaction will increase and equilibrium will shift to the left

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6
Q

what happens to a system at equilibrium if you increase the concentration of products?

A

the rate of reverse reaction increases and equilibrium shifts to the left

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7
Q

What happens to a system at equilibrium if you decrease the concentration of the products

A

rate of forward reaction increases and equilibrium shifts to the right

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8
Q

what happens if you increase the temperature of an exothermic reaction at equilibrium?

A

Reverse reaction is favoured and equilibrium shifts to the left. There is also a decrease in Keq

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9
Q

What happens if you decrease the temperature of an exothermic reaction at equilibrium?

A

forward rate of reaction is favoured and equilibrium shifts to the right. Keq increases.

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10
Q

what happens if you increase the temperature of an endothermic reaction at equilibrium

A

increase in forward rate of reaction and equilibrium shifts to the right. Increase in Keq

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11
Q

what happens if you decrease the temperature of an endothermic reaction at equilibrium

A

increase in reverse rate of reaction and equilibrium shifts to the left. Decrease in Keq

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12
Q

What happens if you add a catalyst to a reversible reaction?

A

Equilibrium will be attained faster.

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13
Q

what happens on a graph if there is an increase n concentration or partial pressure of one substance.

A

sudden increase in one substance

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14
Q

what happens on a graph if there is a decrease in concentration or partial pressure of one substance?

A

sudden decrease in that one substance

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15
Q

what happens on a graph if there is a increase in volume/decrease in pressure of a system?

A

sudden decrease in all gaseous species

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16
Q

what happens on a graph if there is a decrease in volume/increase in pressure of system?

A

sudden increase in all gaseous species

17
Q

what happens on a graph if there is a increase in temperature

A

no sudden changes, gradual increase in certain species depending on whether the reaction is endothermic or exothermic

18
Q

what happens on a graph if there is a decrease in temperature?

A

no sudden changes

19
Q

what does the collision theory state:

A

that reacting substances must collide,
reacting particles must possess the activation energy to result in successful collisions
that they must collide with the correct orientation.

20
Q

what happens to keq when temperature increases in an exothermic reaction

A

Keq decreases

21
Q

what happens to keq when temperature decreases in an exothermic reaction

A

Keq increases

22
Q

what happens to Keq when temperature increases for endothermic reaction

A

Keq increases

23
Q

what happens to keq when you decrease the temperature for an endothermic reaction

A

Keq decreases

24
Q

what happens on a graph when a catalyst is added

A

equilibrium is achieved faster and the line is steeper