mod 5 IQ1 Flashcards
what is the formula for gibbs free energy
ΔG=ΔH−TΔS
change in enthalpy kJ minus change in entropy in kJ/K
what happens when ΔG=0
the process is at equilibrium
what happens when ΔG < 0
the process is spontaneous
what happens when ΔG > 0
process is non-spontaneous
how do you convert degrees to kelvin
add 273.15
what does a reaction need for it to be considered as an equilibrium system
it needs to be spontaneous and reversible and in a closed system
what does a positive entropy mean
disorder
what does a negative entropy mean
order
how do you calculate entropy
ΔS = (entropy of products) - (entropy of reactants)
how do you calculate entropy by looking at the equation
if there is an increase in moles from reactants to products –> entropy increases
if there is a decrease in moles from reactants to products –> entropy decreases
note: if there are multiple states the production of gases increase entropy more
what is an example of an equilibrium system
iron nitrate + potassium thiocyanate
iron nitrate is yellow and potassium thiocyanate is colourless. This produces potassium thiocyanate which is blood red.
IONIC EQUATION:
Fe3+ + SCN- ⇋ FeSCN2+