Mod 5 Flashcards

1
Q

Rates of reaction increases by

A

Increasing concentration of solutions or pressure of gases
Increasing surface area of solid reactant
Increasing temperature
Using catalyst

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1
Q

enthapy

A

The heat (thermal) energy released or absorbed during the reaction (change)

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2
Q

Entropy

A

A measure of the number of possible arrangements of a system
The degree of disorder or randomness in the system

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3
Q

Entropy increases by

A

Volume particles occupy increase
Number of particles increase in system
Temperature of system increase
Substance changes state (s, l, g)

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4
Q

spontaneous reaction

A

A spontaneous reaction: occurs of its own accord, without outside intervention

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5
Q

When G <0

A

spontaneous

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6
Q

When G> 0

A

non-spontaneous

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7
Q

When G=0

A

equilibrium

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8
Q

When H < 0 and S > 0

A

spontaneous
irreverisble fwd rxn

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9
Q

When H < 0 and S < 0

A

spontaneous at low temp
reversible

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10
Q

When H > 0 and S > 0

A

spontaneous at high temp
reversible

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11
Q

When H > 0 and S < 0

A

non- spontaneous
doesnt proceed

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12
Q

Reliability

A

The consistency of experimental results over multiple trials under the same conditions

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13
Q

Validity

A

the extent to which the aim of the experiment is fulfilled fairly.

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14
Q

Zero error

A

An instrument such as a balance should read zero when nothing is on it. If it doesn’t and reads say 0.05g, then all your measurements will be 0.05g more than they should be.

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14
Q

Accuracy

A

the closeness of agreement between an experimental result and the accepted theoretical value.

15
Q

Validity is

A

ACER
aim, constant, equip, range

aim achieved, constant variables, approptriate equipment to reduce error, suitable range

16
Q

Reliability is

A

ROCA
repeat, outlier, consistent, average

repeated with large sample size, outliers removed, results consistent, averaged results

17
Q

Accuracy is

A

SERC
scale, equipment, record, closeness

scale have sufficent graduations, equipment used correct, results recorded with decimal places, measurements close to theoretical values

18
Q

Q > Keq

A

Q shift to left (reactants)
G > 0 (non-spontaneous)

19
Q

Q < Keq

A

Q shift to right (products)
G < 0 (spontaneous)

20
Q

Keq > 1

A

products being favoured
conc products high
conc reactants low

21
Q

Keq < 1

A

reactants being favoured
conc products low
conc reactants high

22
Q

Keq = 1

A

conc reactants = products

23
Q

increase in pressure

A

shift to side with less moles

24
Q

decrease in pressure

A

shift to side with more moles

25
Q

What affects Keq

A

only temp