mock specific Flashcards
what two things does the rate of a chemical reaction depend on?
- the collision frequency
2. the energy transferred during a collision
what are four things the rate of reaction depends on?
- temperature
- the concentration of a solution or the pressure of a gas
- surface area
- the presence of a catalyst
How does a change in temperature affect the rate of reaction? Why?
in order for a reaction to occur, the particles have to collide. increasing the temperature increases the speed the particles move at, and so they collide more frequently, so an increase in temperature increases the rate of a reaction
what effect does concentration have on rate of reaction? Why?
in order for a reaction to occur, particles have to collide. the more concentrated a solution is, the more particles there are per unit volume, so there are more frequent collisions. this means that an increase in concentration increases the rate of a reaction
what effect does pressure have on the rate of a reaction? Why?
in order for a reaction to take place, particles must collide. the higher the pressure, the more particles there are per unit volume, so there are more frequent collisions. this means that an increase in pressure increases the rate of reaction
what effect does surface area have on the rate of a reaction?
in order for a reaction to occur, particles have to collide. increasing the surface area to volume ratio of a solid will increase the amount of the solid exposed to the other reactants, so more frequent collisions will occur. this means that an increase in surface area to volume ratio increases the rate of a reaction
what is a catalyst?
a substance that speeds up the rate of a reaction, without being used up in the reaction itself
are catalysts part of the overall reaction equation?
no
how do catalysts work?
by decreasing the activation energy needed for the reaction to occur. they do this by providing an alternative reaction pathway with a lower activation energy.
give an example of a biological catalyst
enzymes - they catalyse reactions in living things
what is the formula for the mean rate of reaction?
rate of reaction = amount of reactant used or amount of product formed / time
how do you find the rate of a reaction at one particular point in time?
you have to plot a graph and find the gradient at that time
what are the three ways to measure the rate of a reaction?
- precipitation and colour change
- change in mass (usually gas given off)
- the volume of gas given off
what units would you use to measure a product or reactant if it’s a gas?
cm^3
what units would you use to measure a product or reactant if it’s a solid?
grams
what is the most common measurement of time when calculating rate of reaction?
seconds
what are common examples of the units used for the rate of a reaction
cm^3/s, g/s, or mol/s
how do you measure the rate of a reaction using precipitation and colour change? (4 points)
- you can record the visual change in a reaction if the initial solution is transparent and the product is a precipitate which clouds the solution (it becomes opaque)
- you can observe a mark through the solution and measure how long it takes for it to disappear - the faster the mark disappears, the quicker the reaction
- if the reactants are coloured and the products are colourless (or vice versa), you can time how long it takes for the solution to lose (or gain) its colour
- the results are very subjective - different people might not agree over the exact point when the mark ‘disappears’ or the solution changes colour. Also, if you use this method, you can’t plot a rate of reaction graph from the results
how do you measure the rate of a reaction using a change in mass? (5 steps)
- measuring the speed of a reaction that produces a gas can be carried out using a mass balance
- as the gas is released, the mass disappearing is measured on the balance
- the quicker the reading on the balance drops, the faster the reaction
- if you take measurements at regular intervals, you can plot a rate of reaction graph and find the rate quite easily
- this is the most accurate of the three methods because the mass balance is very accurate, but it has the disadvantage of releasing gas straight into the room
how do you measure the rate of a reaction using the volume of gas given off?
- this involves the use of a gas syringe to measure the volume of gas given off
- the more gas given off during a given time interval, the faster the reaction
- gas syringes usually give volumes accurate to the nearest cm^3, so they’re quite accurate. you can take measurements at regular intervals and plot a rate of reaction graph using this method too. you have to be quite careful though - if the reaction is too vigorous, you can easily blow the plunger out of the end of the syringe
what do magnesium and HCl react to produce?
Hydrogen gas
what are the 6 steps to using the reaction between magnesium and HCl to investigate the effect of concentration on the rate of reaction?
- start by adding a set volume of dilute hydrochloric acid to a conical flask and carefully place on a mass balance
- now add some magnesium ribbon to the acid and quickly plug the flask with cotton wool
- start the stopwatch and record the mass on the balance. take readings of the mass at regular intervals
- plot the results in a table and work out the mass lost for each reading. now you can plot a graph with time on the x-axis and loss of mass on the y-axis
- repeat with more concentrated acid solutions. variables such as the amount of magnesium ribbon and the volume of acid used should be kept the same each time - only change the acid’s concentration. This is to make your experiment a fair test
- the three graphs show that a higher concentration of acid gives a faster rate of reaction
what are the 6 steps to using the reaction between sodium thiosulfate and HCl to investigate the effect of concentration on the rate of reaction?
- Sodium Thiosulfate and HCl are both clear solutions. They react together to form a yellow precipitate of sulfur
- start by adding a set volume of dilute sodium thiosulfate to a conical flask
- place the flask on a piece of paper with a black cross drawn on it. add some dilute HCl to the flask and start the stopwatch.
- now watch the black cross disappear through the cloudy sulfur and time how long it takes to fully disappear
- the reaction can be repeated with solutions of either reactant at different concentrations (but only change the concentration of one reactant at a time). the depth of the liquid must be kept the same each time
- The higher the concentration, the quicker the reaction and therefore the less time it takes for the mark to disappear
why should the reaction between sodium thiosulfate and HCl be carried out in a well-ventilated place?
because it releases sulfur dioxide
what do sodium thiosulfate and HCl react together to produce?
sulfur - a yellow, cloudy precipitate
how do you find the mean rate for a whole reaction?
you work out the overall change in the y-axis of the graph (amount of product formed or reactant used up), and divide this by the total time taken for the reaction
how does a reversible reaction reach equilibrium? (high-mark question)
- in a reversible reaction, as the reactants react, their concentrations fall, so the forward reaction will slow down. But as more and more products are made and their concentrations rise, the backward reaction will speed up
- after a while the forward reaction will be going at exactly the same rate as the backward one - the system is at equilibrium
- at equilibrium, both reactions are still happening, but there’s no overall effect (it’s a dynamic equilibrium). This means the concentrations of reactants and products have reached a balance and won’t change
- equilibrium is only reached in a closed system
can a reaction be at equilibrium with unequal amounts of reactants and products?
yes - equilibrium doesn’t mean that the amounts of reactants and products are equal
what does it mean if the position of equilibrium lies to the right?
the concentration of the products is greater than that of the reactants
what does it mean if the position of equilibrium lies to the left?
the concentration of reactants is greater than that of the products
what conditions does the position of equilibrium depend on?
- the temperature
- the pressure (in gases)
- the concentration of the reactants and products
is the reaction from hydrated copper sulfate to anhydrous copper sulfate + water endothermic or exothermic?
endothermic
is the reaction from anhydrous copper sulfate + water to hydrated copper sulfate endothermic or exothermic?
exothermic
what is le chatalier’s principle?
the idea that if you change the conditions of a reversible reaction at equilibrium, the system will react to counteract that change
what can le chatalier’s principle be used for?
it can be used to predict the effect of any changes you make to a reaction system
what happens if you lower the temperature of a reversible reaction at equilibrium?
the equilibrium will move in the exothermic direction to produce more heat. this means you’ll get more products for the exothermic reaction and fewer products for the endothermic reaction
what happens if you raise the temperature of a reversible reaction at equilibrium?
the equilibrium will move in the endothermic direction to try and decrease the temperature. You’ll get more products for the endothermic reaction and fewer products for the exothermic reaction
which reactions at equilibrium are affected by pressure?
those involving gases
what happens if you increase the pressure of a reversible reaction at equilibrium?
the position of equilibrium shifts towards the side where there are fewer molecules of gas - it tries to reduce the pressure
what happens if you decrease the pressure of a system at equilibrium?
the position of equilibrium shifts towards the side where there are more molecules of gas in an attempt to increase the pressure again
what happens if you change the concentration of either the reactants or the products of a system at equilibrium?
the system will no longer be at equilibrium, so it responds to bring itself back to equilibrium
what happens if you increase the concentration of the reactants in a system at equilibrium?
the system makes more products to counteract the change
what happens if you decrease the concentration of products in a system at equilibrium?
the system reduces the amount of reactants to counteract the change
what is a hydrocarbon?
any compound that is formed from carbon and hydrogen atoms only
what is the general formula for alkanes?
CnH2n+2,
what are alkanes?
a homologous series of saturated hydrocarbons
what is a homologous series?
a group of organic compounds that react in a similar way
what is the formula for Butane?
C4H10
what are the properties of shorter hydrocarbons?
- less viscous
- more volatile (lower boiling points)
- more flammable
what are the properties of longer hydrocarbons?
- more viscous
- less volatile (higher boiling points)
- less flammable
what are short-chain hydrocarbons used for? why?
they are used as ‘bottled gases’ - stored under pressure as liquids in bottles - because of their low boiling points
what is the equation for the complete combustion of a hydrocarbon?
hydrocarbon + oxygen -> carbon dioxide + water
during the combustion of a hydrocarbon, what happens to the carbon and hydrogen?
they are both oxidised
why are hydrocarbons used as fuels?
they release a lot of energy when they combust completely
write a balanced symbol equation for the complete combustion of methane
CH4 + 2O2 -> CO2 + 2H20
write a balanced symbol equation for the complete combustion of propane
C3H8 + 5O2 -> 3CO2 + 4H2O
how is crude oil made?
from the remains of an ancient biomass, made up mainly of plankton, that’s been buried in mud
what type of fuel is crude oil?
a fossil fuel
what does crude oil consist of?
different lengths of hydrocarbons and a bit of sulfur
what are the 4 steps to separating hydrocarbons by fractional distillation?
- the oil is heated until most of it has turned into gas. The gasses enter a fractionating column, and everything that remains liquid is drained off
- in the fractionating column there’s a temperature gradient (it’s hot at the bottom and cooler as you go up)
- the longer hydrocarbons have high boiling points. They condense back into liquids early on, when they’re near the bottom. The shorter hydrocarbons have lower boiling points. They condense and drain out much later on, near to the top of the column where it’s cooler.
- you end up with the crude oil mixture separated out into different fractions. Each fraction contains a mixture of hydrocarbons that all contain a similar number of carbon atoms, so have similar boiling points