Mix Flashcards
Chemical equilibrium is said to be dynamic because…
At equilibrium there are reactions continually occurring and the rate of the forward reaction equals the rate of the reverse reaction
Reversible reaction
Takes place in either direction
Balanced equation for the formation of ammonia
N2 +3H2 —-> 2NH3
<—-
Le chatelier’s principle
When a system at equilibrium is subjected to a stress, the equilibrium shifts in such a way as to minimise the effect of the stress
Equation for the reversible reaction between cobalt chloride and water
CoCl4 -2 + 6H2O –> Co(H2O) +
<–
4Cl-
The contact process
Process used to make sulfur trioxide
The Haber process
Process used to make ammonia
Rate of a chemical reaction
The change on concentration in unit time if any one reactant or product
Catalyst
A substance that alters the rate of a reaction but is chemically unchanged at the end of the reaction
Energy Level
A region of definite energy within an atom that electrons can occupy
Line Spectrum
A series of coloured lines against a dark background
The emission spectrum of an element
is characteristic of that element, and is different from that of any other element
The absorption spectrum of an element
The spectrum observed after white light has been passed through the element
The Heisenberg Uncertainty Principle
States that it is not possible to determine at the same time the exact position and velocity of an electron
An Atomic Orbital
A region in space where there is a high probability of finding an electron
The Aufbau Principle
States that electrons will occupy the lowest energy level available
An Energy Sub-level
A group of atomic orbitals within an atom all of which have the same energy
Potassium electron confirguration? How many
(i) energy levels (ii) energy sub-levels
(iii) individual orbitals
1s2 2s2 2p6 3s2 3p6 4s1 Energy levels = 3 energy sublevels = 6 Orbitals = 10
Which is the energy level, energy sublevel and atomic orbital?
3px2
Energy level is the number in front (3)
Energy sub-level is the part of the letter
(X)
Atomic orbital is the entire letter group
(P group)
Ionisation Energy
A measure of the amount of energy needed to remove electrons from atoms
The First Ionisation Energy
The energy required to remove the most loosely bound electron from one mole of gaseous atoms in its ground state
The Second Ionisation Energy
The energy required to remove the most loosely bound electron from each singly charged positive ion in a mole of these ions
The Atomic Radius of an element
Half the distance between the nuclei of two atoms of the element that are joined together by a single covalent bond
Factors that affect the size of the atomic radius
Nuclear charge, number of energy levels and the screening effect of the inner electrons
In a periodic table, does the atomic radius increase or decrease on going left to right across a period?
Decrease
In a periodic table, does the atomic radius increase or decrease on going down a group?
Increase
The first ionisation energy values increase going across a period because?
Of the increase in nuclear charge and the decrease in atomic radius
The first ionisation values decrease going down a group because?
Of the increase on atomic radius and the screening effect of the inner energy levels