Minimals: Diffusion Flashcards
What is the relationship between the absolute temperature (T) and the average kinetic energy of a molecule (E) in a system containing monatomic gas in thermal equilibrium
E= 3/2 KT
K is Boltzmann constant
Define frictional force acting on a molecule with velocity v in an aqueous environment
Ff=fv
F is form factor
What is diffusion
Net flow of material propelled by brownish motion due to a gradient of chemical potential
What is the physical meaning of the diffusion constant
The amount of material transported through a unit surface area in unit time at a unit concentration gradient. It characterize the mobility of molecules.
What is the unit of diffusion constant
M square / s
How does the diffusion constant (D$ depend on temperature (T) and the radius (r) of a spherical molecule
D~ T/r
Write down the equation describing the relationship between the diffusion constant(D)cans the form factor (f)
D= KT/f
K is Boltzmann constant
T is absolute temperature
Which parameters tend toward spatial equilibrium during a diffusion process
The chemical potentials of the components
Write down vant Hoffs law
Pi=osmotic pressure=cRT
R is the universal has constant
T is the absolute temperature
C is the molar concentration of the material in the solution
What is osmosis?
Flow of the solvent to a concentrated solution from the more dilute one, if the two compartments are separated by a semiprermeable membrane. This material flow decreases the concentration gradient between the two solutions.
What is the osmotic pressure
It is the pressure which is able to prevent the solvent flow from the pure solvent to the solution through the semipermeable membrane