mini test 1 main terms Flashcards
van hoff factor
(i) in the osmotic pressure equation
accounts for the molecule’s dissociation, as if they didn’t dissociate
dissociation
when the ions of an electron separate into their own positive and negatively charged ions
electrolyte
a molecule that conducts electricity
gas solubility
how well a gas dissolves into the solvent to form a solution at a certain temperature
this idea sparked Henry’s law
- decreases with temp- kinetic energy increases as temperature increases and can’t stay as dissolved
- directly proportional to pressure
- smaller molecules= higher solubility
- stronger IMF mean greater gas solubility because the molecules are more attracted to eachother and will dissolve better
- increase temp=decreases IMF=decrease gas solubility
Henrys Law
concentrationof a sparingly soluble gas in a liquid is proportional to the partial pressure of the gas
the constant is specific to each gas and liquid pairing
vapor pressure
the pressure exerted by a vapor in equilibrium with its liquid phase at a given temperature
Vapor pressure (vs the pure substance) is increased or decreased based on the solute dissolved in the solution. Some have a stronger IMF with the solute that is dissolved (lower vapor pressure) and some have a weaker bond (higher vapor pressure)
Vapor pressure is completely dependent on the Intermolecular forces AND the temperature
boiling point elevation
the boiling point is when the vapor pressure equals the atmospheric pressure
refers to the non-ideal behavior of a solution having a higher boiling point than that of the pure substance
(Due to an increase of molecules of solute, they block the path for the solution to be able to boil or turn into a gas. There it takes longer to boil and raises the boiling point)
freezing depression
refers to the non-ideal behavior of a solution’s freezing point decreasing lower than that of the pure substance
(The solute disrupts the crystal structure that a pure substance would normally form so it takes longer to freeze in consequence)
colligative properties
Properties that depend on the CONCENTRATION of the solution instead the identities
- boiling elevation
- freezing depression
- osmotic pressure
- vapor pressure
Rauolts Law
the vapor pressure of an IDEAL solution depends on the vapor pressure of each component in the solution and its mole fraction in the liquid mixture
Fractional distillation
A process to separate a mixture of different substances. It is done completely based off of boiling point (lower bp will go first). The mixtures are heated up and the liquid turns into gas. It travels up a tube (a tube regulated with different temperatures) until it starts to condense, it which it condenses in a certain layer. The process is repeated until all f the substances are out.
osmotic pressure
the pressure that is created as water is flowing across.a semipermeable membrane to establish equilibrium
molarity
moles of solute/ volume of solution (L)
molality
moles of solute/ mass of solution (kg)