Mineralogy Intro Flashcards
Minerals (definition)
- One substance
- Inorganic
- Crystalline structure
- Naturally occurring
- Solid
Mineral formation
- precipitation
- metamorphism (scavenging)
- crystallization via melt (igneous)
Metamict minerals
Destruction of internal order via radioactive decay
Mineraloids
Minerals lacking internal order
Ex: amber, no regular repeating crystalline structure
Mineral grouping/classification
Systematic study, identification, and grouping of minerals into a logical classification scheme.
- Dominant anion/anionic complex
- Arrangement of silica tetrahedra in silicate minerals (neso-, ino-, cyclo-, phyllo-, tecto-)
Descriptive mineralogy
Observation, measurement, physical properties; descriptions which identify/describe minerals (color, specific gravity, crystal form, hardness)
Crystallography
Determination of crystal structures of minerals
Crystal chemistry
Examines chemical composition & variability of individual mineral samples
Solid substitutions
Governed by the principles of chemical bonding Ex: Mg Fe; Al Si
Paragenesis
Geologic occurrence
Characteristic occurrence of minerals in geologic setting
Clues to identify minerals in equilibrium in various geologic environments & rock types
Mineral associations (e.g. peridotite: mangle, Mg-rich pyroxene & olivine, no quartz/chromite or magnetite)
Rocks
Solids composed of one or more minerals, glass, or solid organic matter
Crystals
Physical property of minerals
External form
Internal symmetry of a mineral is exhibited in its external form
Bounded by smooth planar surfaces that assume geometric forms with specific angular relationships
Crystal face (3 types)
Euhedral
Subhedral
Anhedral
Euhedral
All crystal faces are developed
Subhedral
Some crystal faces are developed
Anhedral
No crystal faces are developed
Twinned crystal/twinning
The symmetric inter growth of two or more crystals o the SAME substance
Types:
Contact twins
Penetration twins
Merohedral twins
Multiple twins (polysynthetic twins, cyclic twins)
Contact twinning
Simple type of twinning
Definite composition plane is present
Share a single composition surface, often appearing as mirror images across the boundary
Ex: plagioclase, quartz, gypsum, spinel; often exhibit contact twinning
Penetration twinning
Type of simple twinning
Occur if 2+ parts of a crystal appear to interpenetrate each other with the surface between the parts being undefinable and irregular
Appearance of passing through each other in a symmetrical manner
Ex: Orthoclase, staurolite, pyrite, fluorite often show penetration twinning
Merohedral twinning
Type of contact twinning
Lattices of the contact twins superimpose in 3 dimensions, such as by relative rotation of one twin from another
Ex: metazeunerite
Polysynthetic twinning
Type of multiple twinning
Multiple twins are aligned in parallel 3+ individuals are repeated alternately on the same twinned plane
Closely spaced polysynthetic twinning: often observed as STRIATIONS or fine parallel lines on crystal face (e.g. calcite, pyrite)
NOTE: called lamellar (e.g. plagioclase feldspar)
Ex: albite, calcite, pyrite; often exhibit polysynthetic twinning
Cyclic twinning
Type of multiple twinning
Multiple twins are not parallel
Ex: Rutile, aragonite, cerussite, chrysoberyl; often exhibit cyclic twinning, typically in RADIATING pattern
Simple twinning
Simple twins made of only 2 parts
Multiple twinning
Multiple twins have more than 2 orientations
Breakage (3)
Cleavage
Parting
Fracture
Cleavage (6)
- Cubic (e.g. halite)
- Octahedral (e.g. fluorite)
- Dodecahedral (e.g. sphalerite)
- Rhombohedral (e.g. calcite)
- Prismatic (e.g. amphibole)
- Pinacoidal/basal (e.g. biotite)
Parting
Only shown under pressure
Breakage occurs parallel to:
- twinning
- exsolution planes
- crystallographic planes
Fracture
Types:
- Irregular (uneven breakage)
- Conchoidal (seashell-like breakage)
*No preferred direction of breakage
*Volcanic glass
*Isometric minerals
Hardness
*Some minerals display directional differences in hardness
- Talc
- Gypsum [2.2 Fingernail]
- Calcite [3.2 Copper penny]
- Fluorite
- Apatite [5.1 Pocket knife] [5.5 Glass plate]
- Orthoclase [6.5 Steel file]
- Quartz (& ceramic plate)
- Topaz
- Corundum
- Diamond
Tenacity (and its 6 types)
Mineral’s resistance to breakage
Types of tenacity:
- brittle
- malleable
- sectile
- ductile
- flexible
- elastic
Brittle tenacity
Breaks/powders
Malleable tenacity
Hammered into thin sheets
Sectile tenacity
Cut into thin shavings
Ductile tenacity
Drawn into wire
Flexible tenacity
When bent, stays bent/permanently bent
Elastic tenacity
When bent, returns to original shape
Specific gravity
Density ratio (substance to water density)
*Thus, unitless
Metal/native elements: 5-20 sg
Ferromagnesian silicates 2.8-4.5 sg
Light-colored/felsic 1.5-2.7 sg
Magnetism (3 types)
Ferromagnetic: attracted to hand magnet (e.g. magnetite, pyrrhotite)
Paramagnetic: attracted to strong electromagnet (e.g. garnet, pyroxene)
Diamagnetic: neither attracted nor repelled by magnetic field (e.g. quartz, zircon)
Radioactivity
Radioactivity is due to radio isotopes in structure of minerals (alpha, beta, and gamma decays)
Elements: uranium (U), thorium (Th), potassium (K)
Solubility in acid
Carbonate minerals w/HCl contact
Element abundance
Most to least:
O
Si
Al
Fe
Ca
Na
K
Mg
Most common mineral in crust?
Plagioclase feldspar
With inoic radius increasing, hardness & melting point…
Increasing ionic radius:
Increasing melting point
Decreasing hardness
Electrostatic valence bond (evb strength)
S = evb strength = (cation strength)/CN (coordination #; ie # of anions)
evb strength is simply ratio of cation charge to number of anions
Coordination number (CN)
of anions a cation is in contact with
Depends on relative size of cation to anion
CN #’s and geometry:
12 = dodecahdral (e.g. K+, Na+, Ca2+)
8 = cubic (e.g. Fe2+, Ca2+, Na+, Mg+)
6 = octahedral
4 = tetrahedral (e.g. SiO4)
3 = triangular (e.g. CO3)
Anisodesmic
Anisodesmic = evb > 1/2 anion charge
Mesodesmic
Mesodesmic = evb = 1/2 anion charge
Polymorphism types (3)
Reconstructive (e.g. graphite & diamond)
Displacive
e.g. quartz:
low PT = alpha-quartz
high PT = beta-quartz
ligher PT = coesite
highest PT = stishovite
high T/low P = crystobalite
higher T/low P = tridymite
Order-disorder (e.g. orthoclase & microcline = K-feldspars)
high T = 25% Al, 75% Si
low T = 100% Al, 100% Si
Solid solution
Element substitution; if charge & ionic radii are similar
e.g. olivine (Mg2SiO4) & fayalite (Fe2SiO4)
Coupled/paired solid solution / coupled substitution
Two elements simultaneously substitute into a crystal
Maintains overall electrical neutrality and charge constant
Ionic SIZE more important than ionic CHARGE
e.g. plagiclase feldspar Na+/Si4+ (albite) <–> Ca2+/Al3+ (anorthite)
Lattice
Lattice = smallest unit to create reproducable symmetry
Five possible plane lattices (the crystal systems)
Atomic proportion
atomic proportion = weight % / atomic weight
Bowen’s reaction series
High temp to low temp:
Olivine
Pyroxene
Amphibole
Biotite mica
K-feldspar
Muscovite mica
Quartz
High temp to low temp:
Ca-rich feldspar
Na-rich feldspar
Ultramafic / mafic / intermediate / felsic
Ultramafic:
peridotite/komatite
Mafic:
gabbro/basalt
Intermediate:
diorite/andesite
Felsic:
granite/rhyolite
Electroforces & bond strength affect (5 properties)
Hardness
Cleavage
Conductivity
Melting point
Optical properties
Covalent bonds
High melting point
High hardness
High strength
Lmited thermal expansion
Ionic bonds
Moderate hardness
Moderate specific gravity
Soluble in polar solvents
High melting point
Nondirectional bonds / high symmetry
Metallic bonds
Conductive
Soft
Ductile
Malleable
Allows electron discharge
Van der Waals bonds
Polar attraction
Weak
Low hardness
Low melting point
Isodesmic
Uniform bond length
All ionic bonds have same strength
Isometric, tetragonal, haxagonal
Pauling’s rules
Adjacent polyhedrals will share single/pairs of anions so CATIONS are farthest apart
Different cations with HIGH charge tend NOT to share anions
Isomorphism vs polymorphism vs solid solution
Isomorphism:
DIFFERENT chemical composition
SAME structure
Polymorphism:
SAME chemical composition
DIFFERENT structure
Solid solution:
RANGE of compositions within fixed limits
- single substitition
- coubled substitition
XPL vs. PPL
XPL = cross polarized light (analyzer)
- if inserted after the light-material interaction, the original PPL is eliminated and only the light with perpendicular orientation is transmitted
- result is the light which underwent the polarization change
PPL = plane polarized light
- incoming light has a plane polarization (due to a polarizer before the material)
- after light interacts with the material the polarization of certain fraction of light might change (e.g., scattering, polarization rotation due to birefringence)
- see the original PPL + the rotated light
[stopped at p 22 of notes, 9/27/17]