Mineralisation Flashcards
Decomposition steps:
- Reduction of organic matter by detritivores
- Resistant tissue breakdown by fungi
- Decomposition of organic substances by fungi and bacteria
Decomposition of dead organisms and faeces by micro-organisms
Role of ecosystem engineers?
- Transport organic matter and micro-organisms through soil
- Mix organic material and micro-organisms
- Influence soil structure
Humus:
- Contains most resistant substances
- Contains OH and COOH groups
- Negative charge - high CEC (because CEC depends on pH)
- Below pH 7 (more acidic) - carboxyl exchange
Above pH 7 (more basic) - carboxyl and hydroxyl exchange
How does humus bond to metal ion?
Through chelation; humus is the ligand. Trivalent cations are more stable than divalent cations (stronger electrostatic bonds and chelate ring, and due to CFS)
Importance of chelation?
Improves soil formation, removes heavy metals, and prevents unwanted reactions involving essential nutrients. Chelated minerals are also more rapidly absorbed
What is a sesquioxide?
3 O and 2 metal atoms (3:2) e.g. Al2O3
- 50-90% organic matter bound to clay or sesquioxide
Extra bonds -> less decomposition
Phenolic
one or more OH bonded to an aromatic ring
- Most resistant substances of OM
- Form chains
- Can only be broken down by phenol oxydase
How do phenolics reduce decomposition?
Reduce decomposition of other organic molecules by interfering with enzymes.
Immobilisation
when mineralised components are taken up by micro-organisms for production of biomass
Strong competition between micro-organisms and roots for nutrients (from mineralisation) - microbes win
Can C from dissimilation be used for assimilation?
No because it is converted to co2 which disappears from the system