Metals - 3rd Flashcards
what is the structure of a metal?
metallic structure has two components:
- a lattice of positive metal ions
- a ‘sea’ of delocalised electrons
the metal ions each have their usual charges, so zinc ions are Zn 2+, sodium atoms are Na + , etc
- the delocalised electrons were lost by the metal ions, and they move freely through the lattice
metals: picture 1
what is metallic bonding?
metallic bonding is the electrostatic attraction between the positive metal ions and the negative delocalised electrons. it can be thought of as the delocalised electrons ‘gluing’ the metal ions together
how strong is metallic bonding?
metallic bonding is usually a very strong attraction.
what are the properties of metals?
- metals tend to have high melting points
- metals conduct electricity
- metals are malleable
why do metals tend to have high melting points?
as the metallic bonding is usually very strong, so lots of energy is needed to break it.
why do metals conduct electricity?
because the delocalised electrons are free to move through the lattice.
why are metals malleable?
as the layers of metal ions can slide over each other.
what is thermal decomposition reaction?
a thermal decomposition reaction is when heat energy is used to break down a substance.
what do metal carbonates decompose to?
they decompose to form metal oxides and carbon dioxide.
what is downward delivery?
Carbon dioxide is denser than air, so it is often collected by downward delivery. this means it just sinks to the bottom of a tube and stays there until you want to use it.
what is the metal reactivity series?
some metals are more reactive than others. we see this on the reactivity series:
metals: picture 2
why are hydrogen and copper included on the reactivity series?
they are non-metals, but they are included because their positions are important when considering displacement reactions.
what are metal and water reactions?
metal + water -> metal hydroxide + hydrogen
what are two significant observations of a metal and water reaction?
- effervescence : hydrogen gas produced
- solid disappears : due to being used up in the reaction.
how do metals react in metal and water reactions?
the metals which are less reactive than magnesium react so slowly with cold water that you can’t actually tell anything is happening.
how do metals in group one react in metal and water reactions?
they react with water to form metal hydroxides and hydrogen:
metal + water -> metal hydroxide + hydrogen
which metals in group one react similarly?
- the reactions of Li, Na, K with water share some similar observations:
- solid floats as it is less dense than water
- effervescence - hydrogen gas is produced
- solid moves - effervescence propels it around the surface of the water
- solid disappears - it is used in the reaction
- metal hydroxides are alkaline because they donate OH- : NaOH -> Na+ + OH-
What is observed when the universal indicator is added to the water of a metal and water reaction?
- it turns dark blue
- the metal hydroxides are alkalis because they donate OH-
- as the metal gets more reactive, the reactions become more vigorous
- this results in some extra observations for Na and K compared to Li.
What is the reactivity of Lithium, sodium and potassium?
Li- Fast
Na- Faster as it melts
K- fastest as it melts and we can see a lilac flame.
What is the relation between the group 1 metals and reactivity?
The group 1 metals get more reactive as you go down the group as when a group 1 atom reacts, it loses its outer-shell electron to get a full outer-shell.
This happens more easily down the group because:
- the atoms get bigger and have more shells
- the outer-electron is further from the nucleus
- the attraction between the nucleus and the outer-electron is weaker
- so less energy is needed to break the attraction.
What do metal and steam reactants produce?
Metal + steam -> metal oxide + hydrogen
Where is the metal and steam reaction usually conducted?
In a horizontal tube.
metals : picture 1
Explain the process of the experiment of the metal and steam reaction.
- some wet wool is heated to generate steam for the mg to react with.
- the H2 gas produced is ignited to safely destroy it.
Why do metals react with cold water and hot steam to produce different products?
Steam has more energy, so both bonds in the water molecule can break.
How do acids react with metals?
Acids react with metals to form a salt and hydrogen gas:
Acid + metal -> salt + hydrogen