Metallurgy Flashcards
Haemoglobin:Fe then Insulin: _______ & Vit.B-12:____ & Chlorophyll:__.
Insulin:Zn
Vit.B-12:Co
Chlorophyll:Mg
Iron ores?
Haematite Magnetite Siderite Chromite Iron pyrite
Copper ores?
Cuprite Malachite Azurite Copper glance Copper pyrite
Aluminium ores?
Bauxite
Cryolite
Kaolinite/china clay
Corrundum
Lead ores ?
Galena
Cerussite
Anglesite
Zinc ores ?
Sphaterite/ zinc blende
Calamine
Anglesite
Silver ores ?
Argentite/silver glance
Horn silver
Tin ore?
Casserite
Whats gangue & flux?
Gangue/matrix = impurities of sand,stone particles,silica in mineral.
Flux= substances used to remove impurity(gangue).
Low fusible substance is c/d
Slag
Homogeneous mixture of 2 or more metals is c/d
Alloy
For metals having low SRP (s-block elements, Al) which type of metallurgy is opted
Electro metallurgy.
In pyrometallurgy, metals are extracted by
heating.
In hydro metallurgy, metal is extracted by
Dissolving in a suitable solvent.
Pulverisation means
Crushing/grinding. Large lumps of ore are converted into small pieces using ball mill/crusher.
Gravity separation is used for separation of
Oxide ores like Fe2O3, Fe3O4, Cu2O, SnO2
Carbonate ores like FeCO3, ZnCO3
Magnetic separation is used for separation of
Magnetic ores like magnetite (Fe3O4), pyrolusite(MnO2), chromite (FeCr2O4).
Froth floatation is used for separation of
Sulphide ores except Argentite (Ag2S).
Which method is based on adsorption phenomenon?
Froth floatation.
In froth floatation, frother used is
Pine oil
Eucalyptus oil
In froth floatation, collector used is
Sodium ethyl xanthate.
In froth floatation, froth stabiliser used is
Cresol or anniline.
Beyer’s process is for
Red bauxite (Fe impurity)
Serpeck’s method is used in extraction of
Al from white bauxite (silicon impurity).
Calcination is
Heating ore in absence of O2 below its melting point.
Roasting is
Heating of ore in presence of O2 below its melting point.
Roasting: sulphide ores :: calcination:
Calcination: hydroxides/carbonates/hydrated ores
SnO2, an oxide ore is ______ roasted/calcinated.
Roasted (bcz it contains significant amount of S-impurity).
Industries that extract metal from sulphide ores also produce
H2SO4.
Bcz raw material i.e SO2 for preparation of sulphuric acid is produced by roasting of sulphide ores.
Give molecular formula of haematite
Fe2O3
Give molecular formula of magnetite
Fe3O4
Give molecular formula of siderite
FeCO3
Give molecular formula of chromite
FeCr2O4
Iron pyrite is a sulphide ore with formula
FeS2
Formula of malachite & azurite
Malachite = CuCO3.Cu(OH)2 Azurite = 2CuCO3.Cu(OH)2
Copper pyrite is
CuFeS2
Cuprite is
Cu2O
Bauxite
Al2O3.H2O
Formula of cryolite
Na3AlF6
Kaolinite an ore of Aluminium has formula
Al2O3.SiO2.2H2O
Galena, cerussite, anglesite have formula
Galena = PbS Cerussite = PbCO3 Anglesite = PbSO4
Formula of zinc blende, calamine, zincite is
Zinc blende = ZnS
Calamine = ZnCO3
Zincite = ZnO
Argentite/ silver glance =
Ag2S
Horn silver = AgCl
Cassiterite is
Tin ore with formula SnO2
Hydro metallurgy is adopted for reduction of ores of ____?
Ag
Au
*jisme na wo cmpd bante hain
[Au(CN)2]^- phr [Zn(CN)4]^-2
[Ag(CN)2]^- phr [Zn(CN)4]^-2
Which are oxidising & reducing agents respectively in hydro-metallurgy of Au/Ag?
O2 is oxidising agent.
Zn is reducing agent.
Auto-reduction is for
Sulphide ores. As for Cu2S, PbS, HgS.
Here ore irself acts as reducing agent for its oxide.
Smelting (reduction of ore using coke) is done for
ZnO
PbO
Fe2O3 by C at high temp. & by CO at low temp. (1079K)
Reducing agent in thermite process is
Al
Mn3O4 / Cr2O3 —-> .. in presence of Al
Mg is reducing agent in Kroll’s process.
True.
TiCl4 —> Ti + MgCl2 in presence of Mg.
NiO & WO3 are reduced by
H2
Flourspar is
CaF2
Copper matte ?
Cu2S + FeS
Van arkel process is for purification of
Ti, Zr, Hf
Mond’s process id for the purification of
Ni.
Zone refining is for
Si
Ga, Ge, As
Distillation is done for
Zn
Cd
Hg
Liquation is for purification of
Sn
Pb, Bi
Thomas slag is
Ca3(PO4)2
Or
Ca3(PO4) + CaSiO3
For purification of Cu, Ag, Au we use
Electro-refining
Vapour phase refining?
Based on the principle that gaseous product formed in first step must be unstable.
2 methods:
Van arkel process (for Ti, Zr, Hf . Also for W,V.)
Mond’s process (for Ni.)
Poling is a method of _______ and used for ____ ores.
Purification.
Used for Cu & Sn. Ore that has oxide impurity.