Metallic bonding Flashcards
metals typically have the following physical properties:
5 items
high melting temperatures good electrical conductivity good thermal conductivity malleability ductility
all theories of the way that the atoms in a metal are bonded together must explain
the properties of metals
metals typically have…,.or…………electrons in the outer shell
one, two or three electrons in the outer shell
metals typically have…….ionisation energy
low
the electrical conductivity of a metal generally…………. as the number of outer-shell electron
increases
delocalised electrons are
electrons that are not associated with any single atom or any single covalent bond
delocalised electrons are free to
move, they are localised, between any pair of cations
metallic bonding is
the electrostatic force of attraction between the nuclei of metal cations and delocalised electrons
in order to melt a metal it is necessary to
overcome the forces of attraction between the nuclei of the cations and the delocalised electrons to such an extent that the cations are free to move around the structure
metals have a …………………….structre
giant lattice
the number of delocalised electrons per cation determines
the melting point of a metal
group 1 metals have……………..melting temperatures
low
group 2 metals have …………………….melting temperatures
higher
metals in the d-block typically have ………………………..melting temperatures as they have
high as they have more delocalised electrons per ion
a metal with a relatively small cation (ionic radius) will have a
higher melting point as the delocalised electrons are closer to the nucleus, so the force of attraction is greater
when a potential difference is applied across the end of a metal, the delocalised electrons will
be attracted to and move towards the positive terminal of the cell, creating a movement in electrical charge, an electric current
the two factors which determine the ability of thermal conductivity in a metal are
- the free-moving delocalised electrons pass kinetic energy along the metal
- the cations are closely packed and pass kinetic energy from one cation to another
malleability is
whether a metal can be hammered into shape
ductility is
whether a metal can be drawn into a wire
when stress is applied to a metal, the layers of cations
slide over each other and the delocalised electrons with them