Metallic bonding Flashcards
Explain metallic bonding
When there are no nonmetals to gain electrons, the metals become positive and the electrons become delocalized. The cations are surrounded by a sea of electrons.
What gives metals the characteristics of malleability, ductility, conducting electricity and heat, and shine/luster?
The delocalized electrons make it easier to move.
Relationship between delocalized e- and hardness/strength
As the number of delocalized e- increases, the strength and hardness of the metal increases.
Relationship between the size of the cation and the strength of the metallic bond
The smaller the cation, the stronger the metallic bond because they can get closer together.
Na+1 and Mg+2
Mg+2 is smaller and has more delocalized e- so it has a stronger metallic bond.
Why do transition metals have greater delocalized e-?
They have the 4s and 3d so they have greater metallic bonding.
Alloy
Homogeneous mixture (solid solution)
The effects of adding another element to the metal
It changes the properties of the original metal. Disrupts the layers making the metal less malleable and stronger.
Interstitial alloy
The added atoms are smaller than the original metal atoms and fits into the spaces between metal atoms.
Steel
interstitial alloy of iron and carbon
Substitutional alloy
the added atoms are similar in size to the original metal atoms and replace some of the original metal atoms. (Less movement - less malleable and ductile and harder.)
Brass
copper and zinc (substitutional)
Bronze
copper and tin (substitutional)