Intermolecular Forces Flashcards
LDF
exist between all molecules, polar and nonpolar. Weakest IMF.
as mass/molecule size increase, LDF _______
Gets stronger
LDF is the reason why
Nonpolar molecules can condense at a low temp
Formation of Temporary/instantaneous dipole
The electrons are like mobile clouds of negative charge that at any moment the e- density could be greater over one region of the atom or molecule (formation of temporary dipole) which may cause a neighboring atoms’ e- to be disrupted.
Dipole-dipole
between polar molecules, opposite charges in neighboring molecules attract each other
The greater the polarity….
The greater the dipole-dipole
Solubility
Like dissolves like, polar and nonpolar don’t mix. Water is polar, and the more places for H-bonding, the more soluble in water.
Conductivity
Covalent molecules don’t conduct due to no mobile ions and fixed e-
Mpt/Bpt
Strong IMF –> High Mpt/Bpt
Hydrogen bonding
Between molecules that have H bonded to F, O or N. (small atoms with high electronegativity) Very strong dipoles and high Bpts.