metabolic pathways Flashcards
an organisms metabolism transforms matter and energy
true
total chemical reactions of an organism
metabolism
begins with a specific molecule and ends with a producs and each step is catalyzed by a specific enzyme
metabolic pathway
releases energy by breaking down complex molecules into simpler compounds
catabolic pathways
examples of catabolic pathways
Hydrolysis
– Cellular respiration = breakdown of glucose in presence
of oxygen
– “downhill” rxn
consume energy to build
complex molecules from simpler ones
anabolic pathways
examples of anabolic pathways
Dehydration/synthesis rxn
* synthesis of protein from AA
* “uphill” rxn
“do u wanna build a snowman”
Chemical rxns occur when
One substance is combined with another
* Atoms are rearranged in molecules
* Or small molecules combine to form larger molecules
chemical reactions occur when
One substance is broken down into another substance
* Molecules are split into atoms or smaller molecules
Chemical bonds are broken and new bonds form , happpens in most chemical reactions
coupled reaction
when the foward and reverse reactions proceed at the same rate , and the quantities of reactants and products remain constant
chemical equillibrium
capacity to do work (or supply heat)
energy
amount of enrgy to do work
freee energy
stored potential, in position
potential energy
active in motion , motion, measured as temp
kinetic energy
kinetic energy associated w/random movement of atoms or molecules
thermal energy
potential E available for release in a chemical rxn
chemical energy
An object’s position determines its ability to store energy
potential energy / chemical energy
For electrons, farther away from a nucleus it is = more potential
energy it has
* Electrons in an outer shell (farther from the + charged nucleus)
have more potential energy than electrons in an inner shell
true
Principle of Conservation of E
– It cannot be created or destroyed, but it
can be transferred or transformed
first law of thermodynamics
Entropy always increases
– Chemical rxns result in products w/
* More disorder (entropy)
* Less usable energy
second law of thermodynamics
Physical and chemical processes proceed in the
direction that results in lower potential energy and
increased disorder
SPONTANEOUS
They proceed w/o any continuous external influence
– No added E is needeD
Chemical reaction is spontaneous
Spontaneity of a rxn is determined by two factors
amount of potential energy and the degree of order
Products have less potential E than the reactants
. The amount of potential E
Products are less ordered (higher dis-order) than the
reactants
* Disorder = Entropy (∆S)
The degree of order
the potential E of the molecule (heat content)
Enthalpy
Energy that can do work when temp. and pressure are uniform, as in a living cell.
Only processes with a -∆G = spontaneous
Spontaneous processes can be harnessed to
perform work
Gibbs Free-Energy Change (G)
Determines whether a rxn is spontaneous or
requires added energy to proceed
Gibbs Free Energy Change (G)