Mechanisms Flashcards
Give the type of reaction and conditions:
Alkane -> Chloroalkane
Free Radical Substitution
UV light
Cl2
Give the type of reaction and conditions:
Alkene -> Polyalkene
Addition Polymerisation
Low temp
High Pressure
Give the type of reaction and conditions:
Alkene -> Haloalkane
Electrophilic Addition
Hydrogen Halide (g)
Room temp
Give the type of reaction and conditions:
Alkene -> Dibromoalkane
Electrophilic Addition
Br2 in water or other organic solvent
Room temp
Give the type of reaction and conditions:
Alkene -> Alkylhydrogensulphate
Electrophilic Addition
Conc. sulphuric acid
Cold temp.
Give the type of reaction and conditions:
Alkylhydrogensulphate -> alcohol
Hydrolysis
Water
Warm temp.
Give the type of reaction and conditions:
Alkene -> alcohol
Hydration Steam 300°C 60atm H3PO4 catalyst
Give the type of reaction and conditions:
Haloalkane -> alcohol
Nucleophilic substitution
NaOH (aq) or KOH (aq)
Warm under reflux
Give the type of reaction and conditions:
Haloalkane -> nitrile
Nucleophilic substitution
KCN in aqueous ethanol
Boil under reflux
Give the type of reaction and conditions:
Haloalkane -> amine
Nucleophilic Substitution
Ammonia in ethanol in sealed tube
Heat
Give the type of reaction and conditions:
Halo alkane -> alkene
Elimination
KOH in ethanol
Heat
Give the type of reaction and conditions:
Primary alcohol -> aldehyde
Mild oxidation
Potassium dichromate and dilute Sulphuric acid
Heat, distillation
(Without reflux)
Give the type of reaction and conditions:
Secondary alcohol -> ketone
Oxidation
Potassium dichromate with dilute sulphuric acid
Heat, distillation
(no reflux)
Give the type of reaction and conditions:
Aldehyde -> Carboxylic acid
Oxidation
Potassium dichromate with dilute sulphuric acid
Heat under reflux
Give the type of reaction and conditions:
Alcohol -> alkene
Elimination
Conc. sulphuric acid
Heat