Mechanisms Flashcards

1
Q

Name:
The mechanism
The reagents
The conditions for:
Alkane to Halogenoalkane

A

Free Radical Substitution
The Halogen of the Halogenoalkane made
UV light

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2
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Halogenoalkane to Alcohol

A

Nucleophilic substitution
NaOH
Warm aqeuous

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3
Q

Name:
The mechanism
The reagents
The conditions for:
Halogenoalkane to Alkene

A

Elimination
KOH or NaOH
Hot in ethanol

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4
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Halogenoalkane to Nitrile

A

Nucleophilic substitution
KCN
aqueous ethanol

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5
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Halogenoalkane to Primary amine

A

Nucleophilic substitution
Ammonia/NH3
Excess Ammonia

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6
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Alkene to Alkane

A

Catalytic hydrogenation
H2/hydrogen
Ni

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7
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Alkene to Dibromoalkane

A

Electrophilic addition
Br2/ Bromine
No specific conditions/room temperature

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8
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Alkene to Bromoalkane

A

Electrophilic addition
HBr
No specific conditions/room temperature

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9
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Alkene to Alkylhydrogensulphate to Alcohol

A

Electrophilic addition then hydrolysis
H2SO4 then water/H2O
No specific conditions/room temperature

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10
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Alkene to Alchohol

A

Electrophilic addition/direct hydration
Steam
Concentrated H3PO4 or H2SO4

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11
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Alcohol to Alkene

A

Dehydration
Concentrated H2SO4
No specific conditions

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12
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Primary Alcohol to Aldehyde

A

Oxidation
Acidified Potassium Dichromate/
K2Cr2O7/H+
Distillation

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13
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Primary Alcohol to Carboxylic Acid

A

Oxidation
Acidified Potassium Dichromate(K2Cr2O7/H+)
Excess Acidified Potassium Dichromate(K2Cr2O7/H+) AND REFLUX

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14
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Alcohol to Aldehyde to Carboxylic Acid

A

Oxidation
Acidified Potassium Dichromate(K2Cr2O7/H+)
Reflux

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15
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Secondary Alcohol to Ketone

A

Oxidation
Acidified Potassium Dichromate(K2Cr2O7/H+)
Reflux

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16
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Aldehyde or Ketone to Alcohol

A

Reduction
NaBH4
No specific conditions

17
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Aldehyde or Ketone to Hydroxynitrile

A

Nucleophilic addition
KCN and dilute HCl
No specific conditions

18
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Acyl Chloride to Carboxylic Acid

A

Nucleophilic addition elimination
Water/H2O
NPC

19
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Acyl Chloride to Ester

A

Nucleophilic Addition Elimination
Alcohol
NPC

20
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Acyl Chloride to Amide

A

Nucleophilic addition elimination
Ammonia/NH3
NPC

21
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Acyl Chloride to Secondary amide(N-substituted amide

A

Nucleophilic addition elimination
Amide
NPC

22
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Acid Anhydride to Carboxylic Acid

A

Nucleophilic addition elimination
Water/H2O
No specific conditions

23
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Acid Anhydride to Ester

A

Nucleophilic addition elimination
Alcohol
No specific conditions

24
Q

Name:
The mechanism/reaction
The reagents
The conditions for:
Acid Anhydride to Amide

A

Nucleophilic addition elimination
Ammonia/NH3

25
Name: The mechanism/reaction The reagents The conditions for: Acid Anhydride to Secondary amide (N-substituted Amide)
Nucleophilic addition elimination Amide No specific conditions
26
Name: The mechanism/reaction The reagents The conditions for: Carboxylic Acid to Carboxylate salt
Neutralisation NaOH No specific conditions
27
Name: The mechanism/reaction The reagents The conditions for: Carboxylic Acid to Ester
Esterification Alcohol Concentrated H2SO4
28
Name: The mechanism/reaction The reagents The conditions for: Ester to Carboxylic Acid + Alcohol
Acid Hydrolysis H2O Concentrated H2SO4
29
Name: The mechanism/reaction The reagents The conditions for: Ester to Carboxylate Salt + Alcohol
Base hydrolysis NaOH No specific conditions
30
Name: The mechanism/reaction The reagents The conditions for: Benzene to Nitrobenzene
Electrophilic substitution Concentrated HNO3 Concentrated H2SO4
31
Name: The mechanism/reaction The reagents The conditions for: Benzene to Phenylketone
Electrophilic substitution Acyl Chloride Aluminium chloride(AlCl3)
32
Name: The mechanism/reaction The reagents The conditions for: 1° Amine to 2° Amine
Nucleophilic substitution haloalkane NPC
33
Name: The mechanism/reaction The reagents The conditions for: 2° Amine to 3° Amine
Nucleophilic substitution haloalkane NPC
34
Name: The mechanism/reaction The reagents The conditions for: 3° Amine to 4° ammonium salt
Nucleophilic substitution haloalkane NPC
35
Name: The mechanism/reaction The reagents The conditions for: Amine to Akylammonium salt
Acid-base HCl NPC
36
Name: The mechanism/reaction The reagents The conditions for: Nitrobenzene to Phenylamine
Reduction Concentrated HCl Tin(Sn)
37
Name: The mechanism/reaction The reagents The conditions for: Nitrile to Amine
Reduction H2 Nickel(Ni)
38
Name: The mechanism/reaction The reagents The conditions for: Nitrile to Carboxylic Acid
Hydrolysis Dilute HCl No specific conditions