Mechanisms Flashcards

1
Q

KCN conditions

A

aqueous followed by dilute acid

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2
Q

KCN mechanism

A

nuc add

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3
Q

NaBH4 mechanism

A

reduction/nuc add

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4
Q

NaBH4 condition

A

aqueous

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5
Q

esterification conditions

A

heat
strong acid catalyst

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6
Q

saponification

A

ester hydrolysis but in presence of an alkali

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7
Q

Making biodiesel

A

vegetable oils + methanol. (sodium hydroxide on arrow as catalyst)

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8
Q

Vegetable oils and animal fats are

A

esters (lipids) of propan-1,2,3-triol (glycerol

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9
Q

Acid hydrolysis of an ester gives

A

alcohol and carboxylic acid

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10
Q

alkaline hydrolysis of an ester gives

A

alcohol and carboxylate salt (Na/K)

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11
Q

How is soap made?

A

Vegetable oils/animal fats react with KOH (alkaline conditions) to form soap and glycerol.

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12
Q

Nitration of benzene conditions

A

CONC HNO3 and CONC H2SO4
50 degrees C

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13
Q

fiedel crafts acylation conditions

A

anhydrous acyl chloride or acid anhydride (prevents reaction with AlCl3)
AlCl3 catalyst

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