Mechanisms Flashcards
KCN conditions
aqueous followed by dilute acid
KCN mechanism
nuc add
NaBH4 mechanism
reduction/nuc add
NaBH4 condition
aqueous
esterification conditions
heat
strong acid catalyst
saponification
ester hydrolysis but in presence of an alkali
Making biodiesel
vegetable oils + methanol. (sodium hydroxide on arrow as catalyst)
Vegetable oils and animal fats are
esters (lipids) of propan-1,2,3-triol (glycerol
Acid hydrolysis of an ester gives
alcohol and carboxylic acid
alkaline hydrolysis of an ester gives
alcohol and carboxylate salt (Na/K)
How is soap made?
Vegetable oils/animal fats react with KOH (alkaline conditions) to form soap and glycerol.
Nitration of benzene conditions
CONC HNO3 and CONC H2SO4
50 degrees C
fiedel crafts acylation conditions
anhydrous acyl chloride or acid anhydride (prevents reaction with AlCl3)
AlCl3 catalyst