Mechanical 3 Flashcards
How to increase strength
make it difficult for dislocations to move
Microstructure features
Grains
Precipitates
Grains
- Small crystals
- Within each grain lattice of atoms same, but orientation changes from one grain to another
- typical grain size 10-100 microm
Precipitates
- Small particles, typically 1microm or less in size
- lattice structure of atoms in precipitate diff from that in rest of material
Grains and dislocations
- Dislocation can’t cross grain boundary
- refine grain size - yield strength goes up
Hall-Petch equation
effect of grain size
τᵧ = τₒ + k/√d
τᵧ = yield strength in shear τₒ = yield strength of lattice k = constant d = grain size
Precipitates and dislocations
- Dislocation can’t enter particle bc has diff lattice structure
- Dislocations can overcome precipitates by breaking them or looping around
- happens within each grain, think of it as changing value of τₒ
- reduce spacing between precipitate particles, yield strength goes up
Equation describing changing the value of τₒv
τₒ = Gb/L
G = shear modulus b = spacing between atoms L = spacing between precipitates
Work Hardening
-in stress/strain curve, after σᵧ line continues to rise, need more stress to get more strain
Why Work Hardening
- σᵧ stress at which dislocations able to move
- need lot of dislocations moving to get lots of plastic strain
- more dislocations formed as test goes on
Annealing/Tempering
Heating the metal, making grains larger
Microstructures - Simple single-element metals
eg. aluminium, titanium, have simple microstructures
Cold working
Deforming metal at room temp
- produce distorted grains
- inc sctrength
Recrystallisation
Heating cold-worked metal causes new grains to form & grow
Way to get small grain size
Annealing after cold working (recrystallisation)
Precipitation Strengthening
- To get precipitates need metal with more than one element in it
- Bc chem composition of precipitate particles must be diff to that of rest of material (called the matrix)
- atype of strengthening only possible w/ alloys
eg of alloys
- Steel (Fe + C + other elements)
- Titanium Alloys (eg. Ti + 6% Al + 4%V)
- Brasses (eg. Cu + 40%Zn)
- Aluminium
Amount of carbon in steel
-less than 1%, often less than 0.1%
Tricks steel uses
- Sometimes C “dissolves” in the Fe
- Sometimes C combines w/ some Fe to form new material
- Fe atoms have diff lattice structure at high temp & low temp
C dissolves in Fe
- a solid solution
- C can fit into gaps between larger atoms (intersitial)
- In other alloys one atom can substitute for another
A solid solution
when atoms of one element dissolve in the other
Fe atoms and temp
- High temp: Fe has fcc lattice
- Room temp: bcc
- Change is reversible, happens instantaneously on heating and cooling
Carbon dissolving and temp
- Can dissolve in high-temp lattice (holes bigger)
- Cant dissolve in low-temp lattice
- At high temp: material like single-element metal, has grains but no precip, yield strength low as all C in solid soln
- Cooler: C precipitates out of soln, forming Fe3C particles + raising yield strength
High-temp form of Fe
Austenite fcc
Low temp form of Fe
Ferrite bcc
Alloys vs Single-element metals
Alloys better bc they can use precipitation strengthening, creating lots of small particles to impede dislocation motion
At low temps, C
Instead of dissolving, forms separate phase, Fe3C “cementite”
Pearlite
- high yield strength, v high if layers are v thin
- consists of thin, flat layers of ferrite alternating w/ layers of cementite
- 0.76% Carbon content
Ferrite and pearlite
soft, lower σᵧ than pearlite alone
Normalising
Natural cooling, when you take steel out of furnace and let it cool naturally in air
Cooling rate
- cool slowly: grains and pearlite layers larger, strength lower
- Quenching
- Fe atoms change from fcc to bcc instantaneously
Quenching
Taking steel from furnace and dropping into water at room temp
Matensite
- Distorted bcc material
- Sudden quench leaves C atoms stuck where they are as diffusion doesn’t happen instantaneously
- No fe3C forms
- C atoms distort bcc lattice, not enough room for them in bcc holes
Martensite grains
- Lenticular (lens-shaped
- very small grains
Yield strength of martensite
highest yield strength for any heat treatment of steel
Why anneal/temper
- Everything gets bigger and rounder
- Reduce energy, interfaces have energy associated w/ them
- Heating allows atoms to move around (diffuse), reducing no. of interaces + turning long, thin shapes into round, spherical shapes