Measurements and Standards Flashcards

1
Q

what are the environmental standards

A

standards or methods or requirements for land use and subdivision, use of coastal marine area and beds of lakes and rivers, water take and use, discharges, or noise. + monitoring

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2
Q

NZ drinking water standards

A

max acceptable value for drinking water - the concentration of a determinand below which the presence of the determinand does not result in any significant risk to a consumer over a lifetime of consumption

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3
Q

fresh water for pH criterea

A

6.5-9.5

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4
Q

drinking water pH critera

A

6.5-8.5

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5
Q

what does pH measure

A

hydrogen ion concentration

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6
Q

how do you measure pH

A

negative log of hydrogen ion concentration

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7
Q

what does pH in water control

A

solubility of metals (lead is bad for you)

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8
Q

what is alkalinity made up of

A

2 ions carbonate CO3 2- and bicarbonate HCO3-

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9
Q

what is alkalinity

A

acid neutralizing capacity of the water

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10
Q

how is alkalinity measured

A

by measuring the amount of acid (sulfric acid needed to bring the sample to a pH of 4.2)

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11
Q

what does conductivity measure

A

electric conductivity of water

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12
Q

higher value of conductivity means water is a

A

better electrical conductor

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13
Q

how does electrical conductivity increase

A

when more salt (sodium chloride) is dissolved in water

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14
Q

what is conductivity an indirect measurement of

A

salinity

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15
Q

what are the units of conductivity

A

µmhos/cm at 25C or µsiemens/cm

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16
Q

what is the purity of water defined as

A

how resistive it is to electric conductivity

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17
Q

what is salinity

A

classification of ground water

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18
Q

what is salinity based on

A

composition on total dissolved solids content

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19
Q

what type of water can we not drink

A

water over 1000 mg/l dissolved salt content

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20
Q

what is dissolved oxygen

A

amount of gaseous oxygen dissolved in water

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21
Q

how does oxygen get into the water

A

diffusion from surrounding air, aeration, photosynthesis

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22
Q

how much oxygen do we need to support a diverse population

A

5-6 mg/l

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23
Q

what happens when dissolved oxygen levels <2 mg/l

A

Hypoxia

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24
Q

what is hypoxia

A

low or depleted amounts of dissolved oxygen. the bloom of algae, organic matter flourishes, lots of bacteria that eats organic matter and consume a lot of oxygen. dissolved oxygen falls below 2 mg/l = death of organic life

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25
how does temperature affect water
it is a pollutant of water. If you increase the temperature of water, you are getting rid of gas oxygen, dissolved oxygen. aquatic life suffers because of the less amount of oxygen thats present
26
what does turbidity measure
estimates light scattering by suspended particles
27
the more turbid the water
the more muddy the water is
28
high turbid water or prolonged exposure of aquatic species like fish have..
various health effects and even death at certain high concentrations and exposure over high durations
29
what instrument do we used to measure turbidity
nephelometer
30
how does a nephelometer work
measures scattered light at right angles to the source
31
what is a visible indicator of the presence of solids in a water sample
turbidity
32
how is solids used in water analysis
refers to residue left upon evaporation and may be dissolved or undissolved species
33
how is dissolved solids determined
evaporating water and drying the material at 100C. The mass of remaining solids relative to the volume of water evaporated is the measure
34
what compounds make up total solids
everything that doesnt evaporate below 110C. Examples include: inorganic salts, organic material, insoluble salts, soluble salts, metal etc
35
what are undissolved solids responsible for
turbidity or sediment, isolated by simply filtering
36
what are dissolved solids responsible for
hardness of water. Specifically refers to samples isolated by drying at 180C which removes any bound water.
37
what are volatile solids
solids that will burn off at 550C of lower. Includes the vast majority of organic compounds
38
what are fixed solids
solids remaining after burning at 550C and consist largely of inorganic salts. These salts are most directly related to hardness
39
what are settleable solids
solids that will form sediment if not stirred up. Can be determined by simply allowing the material to sit in an Imhoff cone for an hour
40
how to classify water (3)
- compare irons with ions using chemical equivalence - making sure anions and cations balance - use of diagrams and models
41
why do we do water classifications (4)
- help define origin of the water - indicates residence time in the aquifer - aids in defining the hydrogeology - defines suitability
42
how to find equivalent concentration
concentration/(formula weight/charge)
43
chemical equivalence
going from mg/L -> mmoles/L -> meq/L
44
what diagrams can chemical equivalence be plotted on
piper, stiff, pie, depth profile
45
what are piper diagrams
two ternary diagrams projected on quadralinear diagram
46
what are stiff diagrams and how do they work
concentrations of cations are plotted to the left of the vertical axis and anions are plotted to the right (meq/L). The points are connected to form a polygon. Water of similar quality have distinctive shapes.
47
What is hardness defined as
presence of DIVALENT CATIONS (2+)
48
what does hardness cause
water to form scales and a resistance to soap. Hard water doesn't produce lather with soap solutions, but instead produces white precipitate
49
CaCO3 0-75
soft
50
CaCO3 75-150
moderately hard
51
CaCO3 150-300
hard
52
CaCO3 over 300
very hard
53
how is hardness caused in most natural waters
primarily by compounds of calcuim (ca2+) and magnesium (Mg2+)
54
what is the total hardness
sum of carbonate and non carbonate hardness
55
how is hardness calculated
hardnes as CaCO3 = M2+ x 50 (100 is normal but bc theres 2, 100/2 = 50) / EW of M2+ (EW = equivalent weight)
56
How is hardness calculated using titrimetric method
based on a colorimetric reaction that occurs when all hardness ions have been removed from the solution
57
what is hardness mostly
calcium and magnesium
58
non carbonated hardness is only possible if
alkalinity is lower than calcium magnesium concentrations. if not then non carbonated hardness = 0
59
what is the optimum temperature for drinking water
10-15C
60
Dissolved oxygen concentrations are more in
colder water
61
at higher temperatures, the rate of biological activity is
higher if organics are present in the water
62
what does temperature in water affect
various treatment process, especially during wastewater treatment
63
what does taste and odor indicate
contamination as these are the indicators of organics and inorganic compounts
64
how to work out taste and odor
(volume of sample + volume of pure water added to make the sample odor free) / volume of sample
65