M8 From The Universe To The Atom Flashcards

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1
Q

basic evolution of the universe

A
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2
Q

what happened after the big bang

A

Inflation

an extremely short period during which the universe expanded out from a single point

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3
Q

shortly after the BB, what happened in terms of mass

A

the universe did not have an increase in mass

as the universe rapidly expanded outward and occupying more space, the density of the universe decreased causing the universe to rapidly cool

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4
Q

some time after BB, matter was formed from

A

matter was formed from energy
(not hydrogen and helium atoms, antimatter or a continual process of annihilation)

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5
Q

what is annihilation

A

the transformation of matter to energy, it occurs when antimatter and matter pairs collide

when they collide, their mass returns to energy

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6
Q

how were stars initially formed

A

basic matter clumping together in free space

hundreds of millions of years after BB, the universe was relatively calm. once enough mass accrued into a single clump, its own sheer size initiated fusion inside of it, forming a star

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7
Q

what happens when stars die

A

stars under fusion inside their cores

fusion combines smaller elements into larger more complex ( heavy elements) ones to produce energy. when stars die, all the heavy elements formed inside their core are released into the universe

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8
Q

what is an AU

A
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9
Q

what is a solar mass

A
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10
Q

what does hubble’s law tell us

A

used to find out how fast a galaxy is moving away from us, given its distance away

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11
Q

hubble’s law graph

A
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12
Q

hubble’s law spectra

A

red shift - interpreted to mean that galaxies are receding away from us at very high velocities

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13
Q

what is a black body radiator

A

absorbs all incident EM radiation and will emit different amounts of each frequency of light

for a particular temperature, there is a unique spectrum emitted

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14
Q

what happens to spectral radiance as the wavelength of light emitted approaches zero

A

spectral radiance (intensity) approaches zero regardless of the temp of the body

there is no such thing as light with wavelength of zero

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15
Q

why are black bodies called that

A

from the fact that they absorb all colours of light

black bodies come in huge ranges of colours

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16
Q
A

a gas discharge produces a discrete spectrum of light

an incandescent lamp produces a continuous spectrum of light

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17
Q

identify an assumption of each model which determines the shape of its curve

A
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18
Q
A
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19
Q

classing stars TEMP

A

stars at a higher temp will emit radiation at a higher frequency and be bluer

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20
Q

classing stars LUMIOSITY

A

intrinsic brightness of a star is how much energy it gives off

brightness doesn’t take into account the distance

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21
Q

spectral class
highest temp to lowest classes
colour

A

OBAFGKM

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22
Q

temp range of stars

A

2000K - 50 000K

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23
Q

hertzsprung russell diagram

x axis
y axis
3 main groups

A
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24
Q

life of a star starting on main sequence

A

main sequence
red giant
yellow giant
red supergiant
planetary nebula
white dwarf

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25
Q

where are the hot/cold/bright/dim stars

A

most stars begin their lives and live most of their days on the main sequence

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26
Q

our sun on HR diagram

A
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27
Q

HR diagram giants
how bright? how hot?

A

stars migrate off the main sequence and reach later stages of life as giant

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28
Q

HR diagram white dwarves
how bright? how hot?

A

have very long lifetimes

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29
Q

HR diagram how to figure out mass

A

as mas increases, so does luminosity

if a star has more mass, its core is under a greater amount of pressure and fusion occurs more frequently

more fusion means more energy, which is more luminous star

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30
Q

y axis on HR diagram

A

shows luminosity RELATIVE to our Sun
how much energy a star outputs in each stage of their life

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31
Q

x axis on HR diagram

A

temperature in Kelvin

relate temp to its colour, spectral class and what kind of fusion within its core

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32
Q

white dwarves

A

extremely hot (as residual heat from previous stage) , however do not undergo any fusion, so they don’t produce any energy so they’re not luminous

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33
Q

as white dwarves age, where do they move on HR diagram

A

they are always cooling as they age

as their temp drops, they will move slowly to the right of HR diagram

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34
Q

age of the 3 main groups on HR diagram

A

main sequence

then they transition to red giants because they run out of hydrogen fuel for fusion

then becomes white dwarf once fusion stops entirely because ALL of its fuel has run out

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35
Q
A
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36
Q

initial formation of stars

A

protostar (hydrogen gas and stellar dust) held together by gravity

begin to collapse in on itself
pressure increases, generating heat
hot enough to ignite hydrogen and start nuclear fusion

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37
Q

protostar def

A

protostar: a cloud of hydrogen gas and stellar dust in space held together by gravity

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38
Q

the more massive the main sequence star on HR diagram

A
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39
Q

main sequence stars are characterised by…

A

nuclear fusion of hydrogen into helium (2 H into 1 He)

helium has less mass than hydrogen
(this mass defect is converted into energy)
this energy provides pressure outwards that balances inward force of gravity, which stabilises the star

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40
Q

hydrogen fusion 2 varieties

A

proton-proton chain

or

CNO cycle

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41
Q

proton-proton chain

A

form of hydrogen fusion
main process for small main sequence stars

4H→He-4

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42
Q

cno cycle

A

form of hydrogen fusion
main process for big main sequence stars

converts a carbon (catalyst) atom between nitrogen and oxygen to produce
4 hydrogen nuclei –> 1 helium nucleus & energy

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43
Q

after hydrogen fusion

A

when the star runs out of hydrogen fuel, the core starts to contract and outer gas shell expands

temp drops and luminosity increases as star becomes RED GIANT

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44
Q

how are giant stars formed

A

when hydrogen fuel runs out and helium is used as fuel instead

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45
Q

helium fusion requirement and effect on star

A

requires much higher temp to initiate fusion
star overall temp is decreasing but the core temp is increasing

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46
Q

2 processes of helium fusion

A

triple alpha process to carbon
helium fusion into oxygen

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47
Q

< 8 solar masses (He fusion)

A

stop fusion after He runs out and leave core filled with carbon and oxygen

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48
Q

> 8 solar masses (He fusion)

A

continue fusion and leave core filled with iron

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49
Q

how is fusion inside stars initiated

A

by gravitational force

the squeeze from gravity generates heat and pressure in the core

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50
Q

a star would collapse under its own gravity if not for…

A

the outward pressure from fusion in the star’s core

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51
Q

what are protostars formed from

A

basic elements in free space

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52
Q

why is CNO cycle H fusion for larger main sequence stars

A

fusion processes involving heavier elements require more energy to initiate

proton-proton chain involves light elements however since carbon and oxygen are heavier (needs more energy) , fusion can occur

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53
Q

how much energy is released during the proton-proton chain fusion of H to He

A
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54
Q

describe two processes which account of energy production in stars

A
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55
Q

(death) white dwarves are formed when

A

helium runs out and star loses mass (main sequence to giant to white dwarf)

< 8 solar masses (smaller main sequence stars)

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56
Q

( death) neutron stars

A

red giants (from larger main sequence stars) are fueled by He fusion then core is filled with iron
when He runs out, star explodes

supernova (explosion that compresses the star’s core)

neutron star
small and dense core
8-20 solar masses

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57
Q

( death) black holes

A

red giants (largest main sequence stars) are fueled by He fusion which fills core with iron
when He runs out, star explodes

supernova (explosion) due its size, the remnants collapse and form black hole

black hole is infinitely small and dense, prevents light from escaping

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58
Q

death of stars
MS is main sequence

A

small MS < 8 solar masses
red giant (He into C, O)
white dwarf

medium MS 8-20 solar masses
red giant (He into C, O, Fe)
neutron star (medium supernova)

big MS > 20 solar masses
red giant (He into C, O, Fe)
black hole (big supernova)

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59
Q

death of star HR diagram

A
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60
Q

why do stars die

A

they run out of fuel

outward fusion forces are required to balance the inward force of gravity on the star

when fuel runs out, no more fusion, star collapses

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61
Q

the effects of gravity play a significant role in stellar evolution. describe the processes of death for stars with masses above and below 8 solar masses and the role gravity plays

A
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62
Q

what is an arcsecond

A
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63
Q

what is a parsec

A
64
Q

what is parallax (angle)

A

the apparent change in position of an object when you observe it from 2 different points

65
Q

more distant galaxies are receding from Earth at

A

greater rates, proportional to their distance from Earth

66
Q

Hubble’s constant

A

The Hubble constant (denoted H₀) is a measure of the rate at which the universe is expanding

units: kilometers per second per megaparsec (km/s/Mpc)

67
Q

relative mass and charge of protons, neutrons and electrons

A

5 in ten-thousandths column

68
Q

what is an isotope

A

a variant of a chemical element

same no. of protons (which DEFINES the element)

diff no. of neutrons

so different atomic mass, but same atomic number

69
Q

element notation

A

(bigger number)
atomic mass (nucleon number = protons + neutrons)

atomic number (protons)

70
Q

def of amu (atomic mass unit)

A

1/12 of the mass of carbon-12 isotope
(roughly the mass of a single nucleon)

71
Q

cathode ray def

A

beam of electrons
electron beam

72
Q

cathode ray tube composition

A

made of glass
evacuated (vacuum inside to minimise cathode ray collisions with air etc)

73
Q

cathode ray tube “process”

A

the cathode is heated
thermionic emission (giving off charged particles with heating)
the free electrons within a heated metal gain a lot of KE
with sufficient energy, the electrons break free from the surface of the cathode

strong electric field

electrons are accelerate toward anode and some hit the glass, causing fluorescence

74
Q

nature of cathode rays
experimental observation –> inference

A

EO: cause a sharp edged shadow when fired at a cross

I: rays travel in straight lines and can’t pass through solid objects

75
Q

nature of cathode rays
experimental observation –> inference

A

EO: cause a glass wheel to spin along its tracks

I: rays have momentum to transfer and therefore mass

76
Q

nature of cathode rays
experimental observation –> inference
fluorescence

A

EO: collide with glass, causing fluorescence

I: cathode rays have energy

76
Q

nature of cathode rays
experimental observation –> inference
cathode to anode

A

EO: emitted from negatively charged cathode, attracted to positive anode

I: cathode rays are negatively charged

77
Q

nature of cathode rays
experimental observation –> inference
variety of metals

A

EO: emitted from cathodes made from a variety of metals

I: particles comprising cathode rays are contained with every atom (the ELECTRON)

78
Q

what did thomson do

A

charge to mass experiments

79
Q

maths of charge to mass ratio

A

equate centripetal force and magnetic force (on electron)

80
Q

thomson’s experiment
undeflected path

A

balance the electric and magnetic fields so the electrons have an undeflected path

equate Fb and Fe so you have an equation for v

81
Q

thomson’s experiment
deflected path

A

turn off E field
measure deflection
equate Fc and Fb

sub v = E/B into q:m ratio equation

82
Q

thomson’s experiment

A

turn off the E field to measure r

the radius of the magnetic field deflection

83
Q

describe how milikan and thomas each used fields to determine properties of the electron

A
84
Q

q:m value

A
85
Q

Stoke’s Law formula

A
86
Q

what did milikan do

A

measure the charge of a single electron

oil drop experiment

87
Q

milikan’s experiment set up

A

atomiser
variable power source
microscope
opposite parallel plates

88
Q

milikan’s calculations
without E field

A

at terminal velocity, a = 0 (no net force acts on the oil drop)

equate weight force and viscous drag force

formula for r²

89
Q

milikan’s calculations
with E field

A

when v=0

equate electric force and weight force

formula for “q” that involves r³

90
Q

significance of milikan’s results

A

quantised charge: charge only exists in multiples of e charge

breakthrough of idea of quantised charge (packets of particular size)

91
Q

milikan’s experiment method

A

milikan sprayed oil drops through an atomiser and balanced the forces on the oil drop in 2 ways

1: (viscosity of air) balance weight force and viscous drag force

2: (turn on E field) balance weight force and electric force

92
Q

milikan’s experiment
where did the oil drops gain their charge

A

from the atomiser

when the oil drops pass through the small gap in the atomiser they are charged by friction, since they are rubbing against the wall of the atomiser before they are released

93
Q

did the oil drops have velocity with no E field

A

the oil drops were moving at terminal velocity

94
Q

why need terminal velocity to measure radius of oil drop

A

equate mg = 6πηrv (v is terminal velocity)
mass: volume x density
radius: solve for r or r²

95
Q

how did milikan measure the velocity of the drops when the electric field was turned off

A

since v = d/t
measured the distance and time

96
Q

milikan’s experiment
why was the viscous force 0 when the E field was turned on

A

since the Fe and Fg balanced, the velocity was zero
oil was suspended in air

he adjusted the variable power supply to ensure Fg was balanced by Fe

97
Q

how did milikan find the charge of an electron

A

calculating the difference in charge between a number of oil drops

98
Q
A

when placed in E and B fields, DEFLECTION of the cathode rays occurred –> they were charged (not a property of EM waves)

cathode ray made a glass wheel spin –> they had momentum and mass

99
Q

what is geiger-marsden experiment (GM experiment)
outline and hypothesis

A

outline: firing alpha particles at thin sheet of metal foil
(hypothesis: would support Thomson’s atom model [plum pudding is a ball of positive charge, and the plums inside it are the electrons) since the alpha particles are smaller than the atom, would not collide with anything as there was not much solid mass in the atom

100
Q

what is geiger-marsden experiment (GM experiment)
results and implications

A

rutherford scattering
- many particles passed right through the foil
- those that scattered did so in various directions

implications:
- the atom must be a lot of empty space
- must have some very small and dense thing inside (nucleus)
- (this thing) nuclei should be positively charged (proton and neutron) [large repulsive force between the nucleus and pos alpha particles, accounting for the large deflections)

101
Q

what is rutherford scattering

A

Rutherford scattering occurs when the alpha particles are scattered at a variety of angles by an atom (could not be explained by plum pudding)

102
Q

rutherford model of atom

A
103
Q

what is not part of rutherford’s model of atom

A

composition of the nucleus
protons and neutrons weren’t discovered yet

rutherford simply stated that the centre of an atom was a dense positive mass called nucleus

104
Q

discovery of neutrons experiments and chadwick

the experiments

A

Bothe and Becker
fired alpha particles at beryllium and noticed a neutral radiation (no charge) that passed through
it was highly penetrative so they thought it was gamma rays
BUT this radiation have energy 10MeV (much more than gamma rays)

Joliot and Curie
fired the neutral radiation from beryllium through paraffin wax and noticed protons were emitted, that had energy 5MeV

105
Q

discovery of neutrons experiments and chadwick

james chadwick

A

showed the existence of neutral, heavy particles called neutrons

mass similar to a proton
atomic model of nucleus changed from just protons to protons and neutrons

chadwick used conservation of momentum and applied it to alpha, unknown particle, and protons to draw conclusions about the mass of unknown

chadwick measured the final velocity of the protons after collision, and assuming the collisions were elastic, using conservation of momentum and KE to calculate mass of mystery

the fact it had mass showed it was a particle and not radiation

106
Q

what chadwick analysed diagrams

A
107
Q

planck’s contribution to Bohr Model

A
108
Q

Bohr Model of Atom
(upgrade of rutherford model)
3 postulates

A
  1. Electrons exist in stable orbits around the nucleus at discrete radii, with specific energies for each orbit
  2. Electrons emit/absorb energy as EM radiation when moving between orbits, with the energy equal to the difference between the orbital energies
  3. the electron’s angular momentum is quantised
109
Q

Bohr Model of Atom
3 postulates
1st

A

each orbit has a specific energy

these orbits are stable (electrons won’t lose energy)

energy decreases according to an inverse square law as the level increases

110
Q

Bohr Model of Atom
3 postulates

2nd

A

electrons can move between orbits, which releases/absorbs energy (explains line spectra)

111
Q

Bohr Model of Atom
3 postulates

3rd

A

n: orbital level
h: Planck’s constant

112
Q

when jumping to higher energy level, electrons…

A

absorb photons

excitation

113
Q

when falling down an energy level, electrons…

A

emit photon

de-excitation

114
Q
A
115
Q

2 limitations of rutherford model

A
  1. “orbital” decay since it loses energy when the electron accelerates
  2. cannot account for emission spectra
116
Q

5 limitations of bohr model
1st

A

model cannot predict the spectra of atoms other than hydrogen

117
Q

5 limitations of bohr model
2nd

A

model cannot explain why some spectral lines have a higher intensity than others

118
Q

5 limitations of bohr model
3rd

A
119
Q

5 limitations of bohr model
4th

A
120
Q

5 limitations of bohr model
5th

A
121
Q

electron energy levels

A

every atom has diff levels

122
Q

why are the energies negative

A
123
Q

the PHOTON’s energy is equal to the diff between energy levels

formula

A

E=hf is in JOULES

124
Q

emission spectrum

A

when electrons fall down an energy level, they emit photon/s
the wavelengths of these photons are the coloured lines against the black

125
Q

absorption spectrum

A

when you shine white light on an atom, the atom absorbs some of the light’s energy (photons)

the spectrum appears to be continuous with a set of black lines, corresponding to the wavelengths of light that are absorbed by the atoms in the gaseous substance. the photons matching these wavelengths will have an energy that is precisely equal to the amount of energy required for an electron to transition to a higher level.

MOST OF THE ABSORPTION SPECTRUM CAN BE SEEN AS A CONTINUUM OF ALL WAVELENGTHS OF LIGHT. MOST WAVELENGTHS OF LIGHT WILL NOT BE ABSORBED BY THE ATOM, SINCE THE ENERGY OF THE PHOTNS WILL NOT EXACTLY MATCH THE ENERGY REQUIRED TO JUMP LEVELS

126
Q
A

there is no transition from the ground state with an energy difference of 5eV, so electron remains in ground state

127
Q

balmer series qualitative
(ONLY HYDROGEN)

A

a set of specific wavelengths of light emitted by HYDROGEN atoms when an electron falls from the 3rd, 4th, 5th and 6th to the 2nd level

red, light blue, dark blue, purple

128
Q

balmer series quantitative
(ONLY HYDROGEN)

A

energy levels in eV

129
Q

balmer series quantitative
(ONLY HYDROGEN)

A

energy levels in J

130
Q

balmer series quantitative
(ONLY HYDROGEN)

A

from 3, 4, 5, 6
to 2

wavelengths
red: 656nm
light blue: 486nm
dark blue: 434nm
purple: 410nm

131
Q

balmer series formula
wavelength of emitted light

A
132
Q

describe the behaviour of electrons in the Bohr model of the atom with reference to the law of conservation of energy

A

energy conservation is not violated as the energy absorbed or emitted is equal to the difference between the discrete energy levels of the electron

133
Q

when they ask about if an atom can absorb photons with X energy, be careful

A

about which energy level the atom is in

so maybe it could jump from 2 to 3
but it’s in ground state so it can’t

134
Q

evidence for matter as waves

A

Davisson and Germer fired electrons at a nickel crystal and observed how the electrons were scattered

graphing angle of deflection (scattering angle) against intensity looks like an interference pattern (diffraction)

observed electrons scattered in an alternating pattern of maxima and minima around the electron detector

electron’s interference pattern provided conclusive evidence that electrons diffract

135
Q

technicalities of matter waves

A
136
Q

De Broglie’s formula

A

relates the wave nature of a particle (like an electron) to its momentum. It states that every particle can be associated with a wavelength.

De Broglie’s formula tells us that any moving particle, like an electron, has a wavelength (called the de Broglie wavelength) based on its momentum

137
Q
A
138
Q

de Broglie’s hypothesis

A

wave-particle duality, which suggests that matter exhibits both particle and wave behaviour

139
Q

what evidence do we have that light behaves like a particle and matter behaves like a wave? explain how this evidence supports the theory of wave-particle duality

A
140
Q

particle equations…
show
must

A

radioactive decay
“maintain” conservation of mass and charge

141
Q

3 types of radiation (not EM)

A
142
Q

what is an alpha particle

A

a helium nucleus

143
Q

what is a beta particle

A

electron

144
Q

3 radiations
penetrate
ionising ability
range

A

penetrate
alpha: stopped by sheet of paper
beta: sheet of metal
gamma: few cm of lead

way to remember
A: not very penetrating
B: kinda
G: very penetrating

145
Q

penetration vs ionising ability

A
146
Q

what is ionising ability

A

ability to strip electrons from an atom

147
Q

what happens when there are too many nucleons?
radioactive decay

A

the nucleus is too big
- the forced between the nucleons isn’t strong enough to hold it together
- nucleus becomes unstable

ALPHA PARTICLE DECAY
the atom emits 2 protons and 2 neutrons

148
Q

what happens when there are too many neutrons?
radioactive decay

A

number of neutrons is too many?
- small atoms: more than no of protons
- large atoms: 1.5 times no of protons

BETA PARTICLE DECAY
neutron splits into proton and electron (beta particle), the proton stays, the electron is emitted as beta decay

149
Q

what happens when there are too many protons?
radioactive decay

A

nucleus starts to decay
- protons repel each other
- this repulsive force becomes strong enough to break up the nucleus

BETA PLUS DECAY
the proton splits into a neutron and positron (anti-electron/beta+ particle), the neutron stays, the positron is emitted as beta+ decay

150
Q

the neutrino

A

neutrino appears in beta+ decay
antineutrino appears in beta- decay

In beta decay, the total energy before and after the decay didn’t seem to match, suggesting that something was missing.

151
Q

what is n vs z graph

A

x axis: no of protons (z)
y axis: no of neutrons (n)

152
Q

key features of n vs z graph
stability line

A
153
Q

key features of n vs z graph
unstable zones

A
154
Q

isotopes of any size can be stable
t or f

A

false
any isotope with an atomic number than lead (82) won’t be stable

155
Q

apparently isotopes are most stable when the N:Z is 1.5:1

A
156
Q

standard model of matter

A

hadron: combo of quarks
baryon: 3 quarks
meson: quark and anti quark

proton: baryon uud
neutron: baryon udd