M1L3 - Equation of State Flashcards
Any
equation that relates the pressure, temperature, and specific volume of a
substance is called?
equation of state
an equation of state
that predicts the P - v - T behavior of a gas accurately within some properly
selected region
ideal - gas equation of state
the mass of one mole or of a substance in grams, or the mass of one kmol in kilograms.
molar mass M
an imaginary substance that obeys the ideal - gas relation of Pv = RT.
ideal gas
The
deviation of gases from ideal gas behavior at a given temperature and pressure can be
accurately accounted for by a correction factor called the?
compressibilty factor Z
By
curve fitting all the data, the
chart from plotting Z versus
reduced pressure and temperature
is now called?
generalized compressibility chart
Values
of specific volume are also
include on the generalized
compressibility chart through the
variable called?
pseudoreduced specific volume
It has two constants that are determined from the
behavior of a substance at the critical point.
van der Waals Equation of State
This equation is based on five experimentally
determined constants.
Beattie - Bridgeman Equation of State
This is an extension of the Beattie Bridgeman
equation by raising the number of constants to eight.
Benedict - Webb - Rubin Equation of State