Liquids and Solids Flashcards

1
Q

Intermolecular Forces

A

Attractive or repulsive interactions between neighboring molecules

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2
Q

What can intermolecular forces determine?

A

Physical properties such as boiling point, melting point, solubility and density

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3
Q

Intramolecular forces

A

Interactions within a molecule that hold atoms together in a molecule

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4
Q

Types of intermolecular forces

A

London dispersion
Dipole- Dipole
Hydrogen Bonding

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5
Q

Intermolecular force type

London dispersion

A

Exist between all molecules
Weakest IMF
Temporary attractive force

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6
Q

Which intermolecular forces exist between all molecules?

A

London dispersion

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7
Q

Dipole- Dipole

A

Attractive forces between two polar molecules containing permanent dipoles

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8
Q

Permanent dipole

A

Molecules composed of atoms with different electronegativities

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9
Q

What determines the boiling point?

A

Strength of intermolecular force

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10
Q

Hydrogen bonds

A

Strong dipole- dipole interactions betweent a molecules containing a hydrogen atom bonded to N, O, or F

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11
Q

What is the rule for hydrogen bonding

A

Only a hydrogen bond if bonded to a Hydrogen, Oxygen, or Fluorine

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12
Q

Types of intramolecular forces

A

Polar covalent
nonpolar covalent
ionic
metallic bonds

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13
Q

Polar covalent

A

forms between two non metals of slightly different electronegativities

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14
Q

What type of intermolecular interactions are present in polar covalent compounds apart of?

A

dipole-dipole and london dispersion

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15
Q

Nonpolar covalent

A

Form between the same non metals or non metals with similiar electronegativities

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16
Q

What type of intermolecular interaction is present in nonpolar covalent bonds?

A

London dispersion

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17
Q

Ionic bonds

A

Formed between metal and non metal
Transfer of valence e’s from metal to non metal

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18
Q

Cation

A

Postively charged ion

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19
Q

Anion

A

Negativiely charged ion

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20
Q
A
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21
Q

Metallic bonds

A

Form between metal cations and the valence e’s moving freely through lattice

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22
Q

Which are weaker type of forces intermolecular or intramoelcular?

A

Intermolecular

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23
Q

Weakest to strongest intermolecular forces

A

London dispersion < dipole-dipole< H- bonding

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24
Q

Weakest to strongest intramolecular force

A

covalent< ionic < metallic (strongest)

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25
Q

Endothermic

A

Heat required

26
Q

Exothermic

A

Heat released

27
Q

Draw the endothermic process of phase changes (solid to gas)

A
28
Q

Draw the exothermic process for phase change (gas to solid)

A
29
Q

What is the process called for a solid to a liquid?

A

Fusion

30
Q

What is the process from liquid to gas?

A

Vaporization

31
Q

What is the process from a solid to a gas?

A

Sublimation

32
Q

Process from gas to liquid

A

Condensation

33
Q

Process from a liquid to solid

A

Freezing

34
Q

Process from gas to solid

A

Deposition

35
Q

Entropy (S)

A

The disorder or randomness in a system

36
Q

Positive ΔS

A

Increase in randomness

37
Q

Negative ΔS

A

Decrease in randomness

38
Q

Enthalpy (H)

A

Measures the heat in a system

39
Q

What does ΔH represent

A

Amount of hear gained or lost b a system when a reaction is carried out at constant pressure

40
Q

ΔH > 0 means what

A

Heat moves into the system so the reaction is endothermic

41
Q

ΔH < 0 means what

A

Heat moves out of the system and the reaction is exothermic

42
Q

Phase diagram

A

Draw out this diagram and label

43
Q

Triple point

A

Point where all substances exists in the liquid, gas, and solid phase

44
Q

Critical point

A

Point at which the liquid and gas phase become indistinguishbale

45
Q

What is the point called passed the critical point?

A

Supercritical fluid

46
Q

Properties of liquids

Miscibility

A

Degree to which a liquid mixes with another liquid

47
Q

Properties of liquids

Viscosity

A

Measure of a fluid’s resistance to flow

48
Q

Properties of liquids

Surface tension

A

Ability of a liquid surface to resist external forces

49
Q

Properties of liquids

Vapor Pressure

A

equilibrium pressure exerted by a vapor above its liquid

50
Q

Properties of liquids

Which has a lower density liquids or solids

A

Liquids

51
Q

Properties of solids

Ionic solids

A

Hard, non conductive, brittle and have a high melting point

52
Q

Example of ionic solids

A

Table salt (NaCl)

53
Q

Metallic solids

A

Malleable, ductile, conductive, high luster, variable melting pts and hardness

54
Q

Covalent network solids

A

Hard, non coductive, high melting points

55
Q

Example of covalent network solids

A

Diamonds

56
Q

Molecular solids

A

Soft, non conductive, and low melting points

57
Q

Types of unit cells

A

Simple cubic
Body centered cubic
Face centerd cubic

58
Q

Simple cubic

A

1 atom per unit cell
At every corner of the cube

59
Q

Body centered cubic

A

2 atoms per unit cell with 1 atom in the center

60
Q

Face centered cubic

A

4 atoms per unit cell