Liquids and Solids Flashcards
Intermolecular Forces
Attractive or repulsive interactions between neighboring molecules
What can intermolecular forces determine?
Physical properties such as boiling point, melting point, solubility and density
Intramolecular forces
Interactions within a molecule that hold atoms together in a molecule
Types of intermolecular forces
London dispersion
Dipole- Dipole
Hydrogen Bonding
Intermolecular force type
London dispersion
Exist between all molecules
Weakest IMF
Temporary attractive force
Which intermolecular forces exist between all molecules?
London dispersion
Dipole- Dipole
Attractive forces between two polar molecules containing permanent dipoles
Permanent dipole
Molecules composed of atoms with different electronegativities
What determines the boiling point?
Strength of intermolecular force
Hydrogen bonds
Strong dipole- dipole interactions betweent a molecules containing a hydrogen atom bonded to N, O, or F
What is the rule for hydrogen bonding
Only a hydrogen bond if bonded to a Hydrogen, Oxygen, or Fluorine
Types of intramolecular forces
Polar covalent
nonpolar covalent
ionic
metallic bonds
Polar covalent
forms between two non metals of slightly different electronegativities
What type of intermolecular interactions are present in polar covalent compounds apart of?
dipole-dipole and london dispersion
Nonpolar covalent
Form between the same non metals or non metals with similiar electronegativities
What type of intermolecular interaction is present in nonpolar covalent bonds?
London dispersion
Ionic bonds
Formed between metal and non metal
Transfer of valence e’s from metal to non metal
Cation
Postively charged ion
Anion
Negativiely charged ion
Metallic bonds
Form between metal cations and the valence e’s moving freely through lattice
Which are weaker type of forces intermolecular or intramoelcular?
Intermolecular
Weakest to strongest intermolecular forces
London dispersion < dipole-dipole< H- bonding
Weakest to strongest intramolecular force
covalent< ionic < metallic (strongest)
Endothermic
Heat required
Exothermic
Heat released
Draw the endothermic process of phase changes (solid to gas)
Draw the exothermic process for phase change (gas to solid)
What is the process called for a solid to a liquid?
Fusion
What is the process from liquid to gas?
Vaporization
What is the process from a solid to a gas?
Sublimation
Process from gas to liquid
Condensation
Process from a liquid to solid
Freezing
Process from gas to solid
Deposition
Entropy (S)
The disorder or randomness in a system
Positive ΔS
Increase in randomness
Negative ΔS
Decrease in randomness
Enthalpy (H)
Measures the heat in a system
What does ΔH represent
Amount of hear gained or lost b a system when a reaction is carried out at constant pressure
ΔH > 0 means what
Heat moves into the system so the reaction is endothermic
ΔH < 0 means what
Heat moves out of the system and the reaction is exothermic
Phase diagram
Draw out this diagram and label
Triple point
Point where all substances exists in the liquid, gas, and solid phase
Critical point
Point at which the liquid and gas phase become indistinguishbale
What is the point called passed the critical point?
Supercritical fluid
Properties of liquids
Miscibility
Degree to which a liquid mixes with another liquid
Properties of liquids
Viscosity
Measure of a fluid’s resistance to flow
Properties of liquids
Surface tension
Ability of a liquid surface to resist external forces
Properties of liquids
Vapor Pressure
equilibrium pressure exerted by a vapor above its liquid
Properties of liquids
Which has a lower density liquids or solids
Liquids
Properties of solids
Ionic solids
Hard, non conductive, brittle and have a high melting point
Example of ionic solids
Table salt (NaCl)
Metallic solids
Malleable, ductile, conductive, high luster, variable melting pts and hardness
Covalent network solids
Hard, non coductive, high melting points
Example of covalent network solids
Diamonds
Molecular solids
Soft, non conductive, and low melting points
Types of unit cells
Simple cubic
Body centered cubic
Face centerd cubic
Simple cubic
1 atom per unit cell
At every corner of the cube
Body centered cubic
2 atoms per unit cell with 1 atom in the center
Face centered cubic
4 atoms per unit cell