lipids: triglycerides and phospholipids Flashcards

1
Q

are lipids soluble in water?

A

low solubility in water bit high in organic solvents e.g ethanol

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2
Q

what do triglycerides form?

A

fats or oils

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3
Q

how does the number of carbon atoms in a triglyceride affect melting point?

A

the more carbon atoms the higher the melting point as the intermolecular forces are stronger so more energy is needed to overcome them

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3
Q

what is the structure of triglycerides?

A

made from glycerol binded by ester bonds to 3 fatty acids

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4
Q

what bond is between glycerol and fatty acids?

A

ester

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5
Q

how are triglycerides made? what reaction

A

made by a condensation reaction with the relase of 3 molecules of water

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6
Q

how are triglycerides broken down?

A

hydrolysis reaction with the addition of 3 water molecules

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7
Q

what are oils?

A

lipids with short hydrocarbon chain fatty acidsform oils which are liquid at room temp

usually contain unsaturated fatty acids

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8
Q

what are fats?

A

lipids with long hydrocarbon chain fatty acids
solid at room temp

usually contain saturated fatty acids

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9
Q

what is the main function of triglycerides?

A

energy storage

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10
Q

why are triglycerides more efficient energy stores compared to carbohydrates?

A

due to the large ratio of energy storing carbon hydrogen bonds compared to the number of carbon atoms. this allows it to store more energy per unit of mass

fats and oils are the prefered energy store

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11
Q

what are the properties of triglycerides?

A

good thermal insulators and provide mechanical protection to delicate organisms

provide buoyancy (floating) for many aquatic organisms as fat is less dense than water

hydrophobic: some animals coat their fur in oils to make them waterproof

insoluble as they are hydrophobic so triglycerides dont affect water potential

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12
Q

what do all lipids contain?

A

high proportion of CH2 groups and have a low solubility in water but high in organic solvents e.g ethanol

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13
Q

what is the structure of phospholipids?

A

contains a glycerol molecule
2 fatty acid chains which are hydrophobic
hydrophilic phosphate head which contains a phosphate oin

2 fatty acids bond to the glycerol by 2 condensation reactions resulting in 2 ester bonds

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14
Q

how are the 2 fatty acids and glycerol bonded?

A

2 condensation reactions resulting in 2 ester bonds

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15
Q

what are the properties of phospholipids?
how do they arrange themselves in water

A

when in water they are positioned so that the hydrophillic head is exposed to water and hydrophobic tails are not
phospholipid bilayer in membranes

16
Q

what does fluidity of membrane affect?

A

how easy it is for the cell membrane to move

17
Q

how does membranes having only saturated fatty acids influence fluidity?

A

those with only saturated fatty acids are the least fluid

18
Q

how does membranes having only unsaturated fatty acids influence fluidity?

A

least fluid

19
Q

what do lipids containing only saturated fatty acids usually form at room temperature? and why

A

usually form fats at room temperature

this is because fatty acid tails are straight and can pack closely together

stronger forces of attraction form so more energy is needed to break bonds and melt fat so melting point is higher

20
Q

what do lipids containing only unsaturated fatty acids usually form at room temperature? and why

A

form oils at room temp
the double bonds make fatty acid chains less straight so they link and they cant pack as closely together

so forces of attraction are weaker between the fatty acids so less energy is needed to break the nonds and melt the oil so they have a lower melting point