lipids: triglycerides and phospholipids Flashcards
are lipids soluble in water?
low solubility in water bit high in organic solvents e.g ethanol
what do triglycerides form?
fats or oils
how does the number of carbon atoms in a triglyceride affect melting point?
the more carbon atoms the higher the melting point as the intermolecular forces are stronger so more energy is needed to overcome them
what is the structure of triglycerides?
made from glycerol binded by ester bonds to 3 fatty acids
what bond is between glycerol and fatty acids?
ester
how are triglycerides made? what reaction
made by a condensation reaction with the relase of 3 molecules of water
how are triglycerides broken down?
hydrolysis reaction with the addition of 3 water molecules
what are oils?
lipids with short hydrocarbon chain fatty acidsform oils which are liquid at room temp
usually contain unsaturated fatty acids
what are fats?
lipids with long hydrocarbon chain fatty acids
solid at room temp
usually contain saturated fatty acids
what is the main function of triglycerides?
energy storage
why are triglycerides more efficient energy stores compared to carbohydrates?
due to the large ratio of energy storing carbon hydrogen bonds compared to the number of carbon atoms. this allows it to store more energy per unit of mass
fats and oils are the prefered energy store
what are the properties of triglycerides?
good thermal insulators and provide mechanical protection to delicate organisms
provide buoyancy (floating) for many aquatic organisms as fat is less dense than water
hydrophobic: some animals coat their fur in oils to make them waterproof
insoluble as they are hydrophobic so triglycerides dont affect water potential
what do all lipids contain?
high proportion of CH2 groups and have a low solubility in water but high in organic solvents e.g ethanol
what is the structure of phospholipids?
contains a glycerol molecule
2 fatty acid chains which are hydrophobic
hydrophilic phosphate head which contains a phosphate oin
2 fatty acids bond to the glycerol by 2 condensation reactions resulting in 2 ester bonds
how are the 2 fatty acids and glycerol bonded?
2 condensation reactions resulting in 2 ester bonds
what are the properties of phospholipids?
how do they arrange themselves in water
when in water they are positioned so that the hydrophillic head is exposed to water and hydrophobic tails are not
phospholipid bilayer in membranes
what does fluidity of membrane affect?
how easy it is for the cell membrane to move
how does membranes having only saturated fatty acids influence fluidity?
those with only saturated fatty acids are the least fluid
how does membranes having only unsaturated fatty acids influence fluidity?
least fluid
what do lipids containing only saturated fatty acids usually form at room temperature? and why
usually form fats at room temperature
this is because fatty acid tails are straight and can pack closely together
stronger forces of attraction form so more energy is needed to break bonds and melt fat so melting point is higher
what do lipids containing only unsaturated fatty acids usually form at room temperature? and why
form oils at room temp
the double bonds make fatty acid chains less straight so they link and they cant pack as closely together
so forces of attraction are weaker between the fatty acids so less energy is needed to break the nonds and melt the oil so they have a lower melting point