Lipids - triglycerides Flashcards

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1
Q

what are lipids

A

commonly known as fats and oils. these contain the elements hydrogen, oxygen and carbon

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2
Q

what is the difference between fats and oils

A

lipids that are solid at room temperature are fats
lipids that are liquid at room temperature are liquids

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3
Q

are lipids soluble or insoluble in water

A

insoluble

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4
Q

why are lipids insoluble

A

they are non polar molecules as the electrons in the outer orbitals that form the bonds are more evenly distributed than in polar molecules. this means there are no positive or negative areas within the molecules so do not attract water molecules

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5
Q

what substance does lipid dissolve in

A

alcohol

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6
Q

are lipids polymers

A

no. they are large, complex molecules called macromolecules

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7
Q

why don’t lipids form polymers

A

lipids aren’t built from repeating units or monomers

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8
Q

what is a triglyceride

A

made by combining one glycerol molecule with three fatty acids.

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9
Q

what group of chemicals does glycerol belong to

A

alcohols.

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10
Q

what group of acids do fatty acids belong to

A

carboxylic acids

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11
Q

what do fatty acids consist of

A

a carboxyl group (COOH) with a hydrocarbon chain attached.

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12
Q

describe glycerol

A

has 3 carbon atoms. it is an alcohol so has free -OH groups. it has 3 -OH groups which are important to the structure of triglycerides

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13
Q

describe a fatty acid

A

have a carboxyl on one end, attached to a hydrocarbon tail, made of only carbon and hydrogen atoms.

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14
Q

how many carbons can fatty acids have

A

anything from 2 to 20 carbons long

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15
Q

why is the fatty acid an acid

A

the carboxyl group ionises into H+ and -COO group. this structure is therefore an acid because it produces free H+ ions

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16
Q

what are saturated fatty acids

A

fatty acid chains that have no double bonds present between the carbon atoms. they are saturated because all the carbon atoms form the maximum number of bonds with hydrogen atoms

17
Q

what are unsaturated fatty acids

A

a fatty acid with double bonds between some of the carbon atoms

18
Q

if there is one double bond present it means..

A

it is a monounsaturated fatty acid

19
Q

if there is two or more double bonds it means..

A

it is a polyunsaturated fatty acid

20
Q

what does the presence of the double bond in the fatty acid do

A

causes the molecule to kink or bend and they therefore cannot pack closely together. this makes them liquid at room temperature

21
Q

why are plants more healthier

A

they contain unsaturated triglycerides which normally occur as oils and tend to be more healthy than the triglycerides in fats (solids).

22
Q

what can excess saturated fats cause

A

coronary heart disease. an excess of any type of fat can lead to obesity

23
Q

what does a triglyceride consist of

A

one glycerol molecule bonded to three fatty acids

24
Q

what do both fatty acids and glycerol molecules have

A

hydroxyl groups

25
Q

how do triglycerides form

A

both fatty acids and a glycerol molecule have hydroxyl group. when these groups react it leads to the formation of three water molecules and bonds between the fatty acids and glycerol molecules

26
Q

what bond form when glycerol and fatty acids react

A

ester bonds

27
Q

what type of bond is an ester bond

A

covalent

28
Q

what type of reaction occurs when a triglyceride is formed

A

esterification/condensation

29
Q

what needs to be supplied to break down triglycerides

A

three water molecules

30
Q

what type of reaction occurs when triglycerides are broken down

A

hydrolysis

31
Q

what are the functions of triglycerides

A
  • energy source
  • energy store
  • insulation
  • buoyancy
  • protection
  • steroid hormones
  • cell structure
32
Q

how are triglycerides used as a source of energy

A

triglycerides can be broken in respiration to release energy and generate ATP. the ester bonds are hydrolysed and then the glycerol and fatty acids can be broken down completely to carbon dioxide and water. respiration of a lipid produces more water than respiration of sugar

33
Q

how are triglycerides used as an energy store

A

insoluble in water so can be stored without affecting the water potential of cells. one g of fat releases twice as much energy as 1g of glucose. this is because lipids have a higher proportion of hydrogen atoms than carbohydrates and almost no oxygen atoms.

34
Q

how are triglycerides used as a form of insulation

A

adipose tissue is a storage location for lipids in whales acting as a heat insulator. lipids in nerve cells act as electrical insulators

35
Q

how are triglycerides used to provide buoyancy

A

fat is less dense than water so is used by aquatic animals to help them stay afloat

36
Q

how do triglycerides provide protection

A

humans have fat around delicate organs as the kidneys