Lipids Flashcards
Primarily hydrocarbon chains and rings (few functional groups) are important in lipids because….
Strongly hydrophobic – useful for waterproofing (cells, leaves, fur and feathers)
Many C-C and C-H bonds are useful for lipids because….
High potential energy when oxidized – good low mass storage molecule
Low electrical conductivity is useful for lipids because….
Good insulator for nerves (myelin sheaths)
Slow to heat and cool is useful for lipids because….
Provides good thermal insulation – subcutaneous fats in whales, seals, waterbirds, humans
Identify 4 categories of lipids
- Triglyceride (or triacylglycerol) = fats & oils
- Steroids
- Waxes
- Phospholipids
What are the properties of a saturated triglyceride? + give an everyday example
Saturated fats have no double bonds in the hydrocarbon chains of their fatty acids. Stearic acid, found in most mammals and palmitic acid (found in palm oils) are saturated.
What are the properties of an unsaturated triglyceride? + give an everyday example
Monounsaturated fatty acids have one double bond, while polyunsaturated fatty acids have two double bonds. Oleic acid, found in olive oil, is monounsaturated. Linoleic and linolenic acids, found flax seed oil, and most fish oils are polyunsaturated.
Ester Bond
O
||
- C - O - C
Why are trigycerides considered macromolecules but not technically polymers?
While polymers can be extended ad infintum with the addition of more monomers, fats have only three fatty acid residues.
What are the properties of a phospholipid?
Phospholipids are primarily made from triglycerides but one fatty acid is replaced by a phosphate that in turn is usually attached to a small hydrophilic molecule. The hydrophilic “head” orients away from the hydrophobic tails and produces an amphiphilic molecule.
Review how phospholipids form a stable bilayer in water.
Phospholipids can form a stable bilayer in water with the heads of both layers oriented outward and the hydrophobic tails sandwiched in a water-free layer between them. Such bilayers always separate an inner watery environment (cytoplasm) from and outer watery environment
What is a steroid? What molecule are all other steroids derived from?
A lipid soluble hormone derived from cholesterol.
What functions do steroids play in living things?
Cholesterol is an important constituent of animal cell membranes, giving them strength and viscosity that helps to compensate for the lack of a cell wall and making them more resistant to solidifying when cooled. Steroids are hormones derived from cholesterol that play important roles in maturation, sexual function, stress, mineral balance (especially sodium) and, in other animals, molting and metamorphosis.
Basic Structure of a Steroid
Bunch of hexagons thrown together….