lipids Flashcards

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1
Q

what do lipids contain

A

large amounts of C and H and smaller amounts of O

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2
Q

what are the 3 most important lipids

A

triglycerides (fats and oils), phospholipids and steroids

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3
Q

are lipids soluble or insoluble in water

A

insoluble as they’re not polar

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4
Q

are lipids a polymer

A

not polymer, but are made of different components.
is a macromolecule.

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5
Q

structure of triglycerides

A
  • 1 molecule of glycerol and 3 fatty acids
  • contain C, H + O
  • macromolecules
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6
Q

what are the functions of triglycerides (5 functions)

A
  • energy source = broken down in respiration to release energy + generate ATP
  • energy store = stored without affecting the water potential of cell as triglycerides are insoluble in water
  • insulation = lipids around the nerve cells act as an electrical insulator
  • buoyancy = fat is less dense than water so used by aquatic mammals to stay afloat.
    -protection = fat around organs act as a shock absorber
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7
Q

what is glycerol made up of

A

3 carbon atoms, each with a hydroxyl group attached and hydrogen atoms occupying the remaining positions.

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8
Q

what does a single fatty acid molecule contain

A

an acid group (COOH) attached to a hydrocarbon chain.
the hydrocarbon chain can be 2-20 carbons long.

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9
Q

what is a saturated fatty acid

A

every carbon atom in the chain is joined by a single bond (c-c)

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10
Q

what is an unsaturated fatty acid

A

at least one double bond between the carbon atoms (c=c)

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11
Q

what is a polyunsaturated fatty acid

A

contains many double bonds between the carbon atoms

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12
Q

what is the bond between glycerol and fatty acid chains called

A

an ester bond - formed in esterification ( a type of condensation reaction).

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13
Q

what do most phospholipids contain

A
  • a diglyceride
  • a phosphate group
  • a simple organic molecule such as chlorine
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14
Q

is the number of carbon atoms a fatty acid usually has even or odd

A

an even number

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15
Q

where are phospholipids found

A

main component in cell surface membranes in both eukaryotic and prokaryotic cells.

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16
Q

what is the structure of phospholipids

A

they have fatty acid tails, that are hydrophobic, and a phosphate head, that is hydrophilic, attached to a glycerol molecule.
there are only 2 fatty acids bonded to a glycerol molecule as one has been replaced by a phosphate ion (head).

17
Q

why are phospholipids amphipathic (having both hydrophilic and hydrophobic parts)

A

they have both hydrophobic and hydrophilic parts.
resulting in the molecules forming bilayers / monolayers in water.

18
Q

what type of molecule are phospholipids

A

macromolecules

19
Q

why is a bilayer formed with phospholipids

A

when in water, the phosphate group has a negative charge (polar) which attracts to the water. whereas, the fatty acid tails are non-polar and therefore repelled by the water.
forming a layer on the surface of the water with heads in the water and tails sticking up out of the water

20
Q

what is the structure of the bilayer

A

2 rows of phospholipids - hydrophobic tails pointing inwards and hydrophilic heads pointing outwards.

21
Q

what do phospholipids form other than bilayers

A

micelles - tiny balls with tails tucked inside and the heads pointing into the water.

22
Q

what is created when a phospholipid bilayer forms due to the presence of hydrophobic fatty acid tails

A

a hydrophobic core - acts as a barrier to water-soluble molecules.

23
Q

is the phosphate head soluble or insoluble in water

A

soluble - polar
(hydrophilic)

24
Q

are the fatty acid tails soluble or insoluble in water

A

insoluble - non-polar
(hydrophobic)

25
Q

where is cholesterol found

A

cell membrane of eukaryotic cells.
fits in between phospholipids.

26
Q

what is the structure of cholesterol

A

made from 4 carbon based rings and a hydrocarbon tail.
the ring has a polar hydroxyl (OH) group.
have hydrophobic and hydrophilic regions - allowing them to exist in the bilayer of the membrane.

27
Q

where are molecules of cholesterol synthesised (made)

A

in the liver + transported via the blood

28
Q

what does cholesterol affect in the cell membrane

A

the fluidity and permeability of the cell membrane
- disrupts the close-packing of phospholipids, increasing the rigidity of the membrane (makes it less flexible).
- acts as a barrier = prevents water soluble substances from diffusing across the membrane.

29
Q

what are molecules of cholesterol used to produce

A

steroid -based hormones = oestrogen, testosterone and progesterone

30
Q

what component does a phospholipid contain that is absent in a triglyceride

A

phospate group

31
Q

how many ester bonds do fatty acids and glycerol contain

A

3

32
Q

when does an ester bond form

A

when a hydroxyl (OH) group from the glycerol bonds with the carboxyl (COOH) group of the fatty acid

33
Q

what is the reaction that breaks ester bonds during the breakdown of the triglyceride molecule

A

hydrolysis reaction - 3 water molecules are taken in the reverse reaction to the condensation.

34
Q

what reaction is an ester bond

A

condensation

35
Q

what joins together during esterifiction

A

3 fatty acid molecules and 1 glycerol molecule to form a triglyceride.