Lipids Flashcards
What are lipids composed of?
Carbon, hydrogen, oxygen
How percentage of diet should be fat?
30%
Less than 9% saturated
Less than 1% trans
What does hydrophobic and hydrophilic mean?
Hydrophobic - avoids water (most lipids)
Hydrophilic - soluble
What are fatty acids biological composition?
Fats are an organic acid, with a carbon backbone
Chain of carbon and hydrogen atoms and an acid group (COOH) at one end, and a methyl group (CH3) at the other
What is the difference between a small and long carbon chain?
small - 6-10 carbon bonds, primarily in diary
Med/large - 12/24, in meats, fish
What is the omega end and what is the alpha end?
Omega end - methyl group (CH3)
Alpha end - carboxyl acid (-COOH)
What is a triglyceride?
Lipids composed of three fatty acids attached to glycerol.
Condensation reactions must occur to combine hydrogen atom (from glycerol) and hydroxyl group (from fatty acid) - forms water molecule and bond between other two molecules.
Most contain more than one type of fatty acid
What is a saturated fat?
Fat that is fully loaded with hydrogen bonds
What is an unsaturated fat?
A fat with missing hydrogen bonds
What is the difference between monounsaturated and polyunsatured?
mono - one double bond
Poly - more than one double bond
(Also triple bonds)
What is the difference between Trans and cis unsaturated fat?
Trans - H atoms opposite sides. (Chain is straight - solid at room temp)
Cis - H atoms same side (bent configuration - liquid at room temp)
What are some characteristics of solid fats and oils?
Firmness - shorter the carbon chain, the softer far is at room temp
Stability - oxidation of fats spoils them, saturated fats most resistant to oxidation
Hydrogenation - unsaturated fats become saturated (adds H)
What are phospholipids?
2 fatty acids joined to a glycerol backbone.
Lecithin (eggs, liver, soybeans, wheat germ)
Used as emulsifiers - fat suspended in blood/body fluids
Soluble in water/fat - helps fat-soluble substances (vitamins, hormones) pass easily in and out of cells.
Hydrophilic head and hydrophobic body
What are sterols?
Compounds with a multiple ring structure
Cholesterol!! Cannot be used for energy - body’s make 75% of it (endogenous)
Found in bile acids, sex hormones, vitamin D
Serves at starting material/structural component of cell membranes
Is cholesterol essential in the diet?
No, nearly all cells are capable of synthesising cholesterol