Lipids Flashcards

1
Q

Are lipids polar or non polar molecule

A

Non polar

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2
Q

Lipids are large complex molecules known as […]

A

Macromolecules

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3
Q

Are lipids built from monomers

A

No
-> instead they have a chain of carbon atoms that act as a backbone

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4
Q

What functional group do fatty acid chains contain

A

(-COOH)
- attached to the hydrocarbon chain

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5
Q

Saturated fatty acid chains have no […] bonds and tend to be […] at room temperature

A

Double, solid

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6
Q

Fatty acid chains that have double bonds present between the carbon atoms are called […]

A

unsaturated

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7
Q

What effect does the double bond have on the structure of a fatty acid chain

A

The double bond causes the molecule to bend or kink: so they are shaped like /—\
+ This stops them being able to pack tighter nicely, making them dense
-> therefore they tend to be oils at room temp

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8
Q

Where are hydrogens in the cis arrangement

A

On the same side of the double bond

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9
Q

Where are hydrogens in the trans arrangement

A

On opposite sides of the double bond

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10
Q

How is a triglyceride made

A

1 glycerol + 3 fatty acid chains
(The length of the hydrocarbon chain is typically 14-16 carbon atoms)
Formed in condensation

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11
Q

glycerol + 3 fatty acids ->

A

triglyceride + 3H2O

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12
Q

Glycerol structure

A

….H
….|
H-C-OH
H-C-OH
H-C-OH
….|
….H

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13
Q

The reaction between alcohol and carboxylic acid functional groups is called […]

A

esterification

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14
Q

Ester functional group

A

-COO

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15
Q

an ester bond is the bond between

A

The oxygen and carbons that connect the molecules

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16
Q

Triglycerides can be broken down in

A

Hydrolysis

17
Q

Note 2 go look at formation of a triglyceride (drawn out)

A

👎👎👎

18
Q

What are phospholipids

A

Modified triglycerides

19
Q

Difference between triglycerides and phospholipids

A

In phospholipids, one of the fatty acid chains is replaced by an inorganic phosphate ion (PO43-)

20
Q

Is a phospholipid molecule polar or non polar

21
Q

Phospholipids have 2 hydrophobic, non polar

A

Fatty acid tails

22
Q

Phospholipids have a charged (polar), hydrophilic

A

Phosphate head

23
Q

Why are phospholipids called surfactants

A

They form a 2 layered sheet formation (bilayer)
-> hydrophobic tails inwards, hydrophilic phosphate head outwards to the aq environment
—> this separates the cytoplasm from the outer aq area

24
Q

Why is the bilayer arrangement of phospholipids important

A

Allows them to separate the aqueous environment + then allows formation of membrane bound organelles

25
What are sterols
Steroid alcohols -> another type of lipid
26
Sterols structure
- complex alcohol molecules based on a four ring structure, with a hydroxyl group at one end - The hydroxyl group is polar and hydrophilic, and the rest of the molecule is hydrophobic
27
The body manufactures cholesterol primarily in the […]
liver and intestines
28
What does cholesterol do in the cell membrane
-> It adds stability to the cell membrane and regulates their fluidity •At low temperatures it keeps the membrane fluid •At high temperatures it stops it becoming too fluid
29
how the properties of cholesterol molecules relate to their functions in living organisms
- in eukaryotic cells cholesterol molecules help support the structure of the cell membrane and stabilise the cell membrane - has a small size and flattened shape which allows it to fit in between the phospholipid molecules in the membrane - their non-polar hydrophobic tail is attracted to the phospholipid hydrophobic tails in the centre of the membrane, packing the phospholipids closer together making adding stability to the membrane and regulating the fluidity of the membrane - the hydroxyl group is polar and therefore hydrophilic and the rest of the molecule is hydrophobic, so it's able to create a further barrier
30
how the properties of triglyceride molecules relate to their functions in living organisms
energy storage in plants and animals - some bacteria use triglycerides to store both energy and carbon - good for storage because long hydrocarbon tails of the fatty acids contain lots of chemical energy - lots of energy is released when they're broken down - 2x more energy than carbohydrates because of tails - insoluble so don't cause water to enter the cells - Storage molecules need to be insoluble so they don't release their contents when in contact with water - triglycerides bundle together as insoluble droplets in cells because the fatty acid tails are hydrophobic - the tails face inwards shielding themselves from water
31
how the properties of phospholipid molecules relate to their functions in living organisms
found in the cell membranes of all prokaryotes and eukaryotes - make up the phospholipid bilayer - hydrophilic heads and hydrophobic tails, so they form a double layer with their heads facing out towards the water on either side - the centre of the bilayer is hydrophobic so water soluble substances can't easily pass through it - acts as a barrier