Lipids Flashcards

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1
Q

What elements do lipids contain?

A

Carbon, hydrogen and oxygen

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2
Q

What are lipids commonly known as?

A

Macromolecules- not built from monomers

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3
Q

Why are lipids non polar?

A

Electrons in the outer orbital are evenly distributed so there are no positive/negative regions- lipids are insoluble in water (hydrophobic)

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4
Q

What is a triglyceride made of?

A

One glycerol and three fatty acids

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5
Q

What groups do glycerol and fatty acids belong to?

A

Glycerol- alcohol

Fatty acid- carboxylic acid

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6
Q

How are ester bonds formed between a glycerol and fatty acids?

A

The hydroxyl groups on both molecules interact, forming 3 ester bonds and 3 water molecules (condensation reaction)
This reaction is called esterification

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7
Q

How can triglycerides be broken down?

A

3 water molecules need to be supplied- hydrolysis reaction

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8
Q

What is the difference between saturated and unsaturated fatty acids?

A

Saturated- no double bonds between carbon atoms
Unsaturated- there are double bonds between some of the carbon atoms
Monounsaturated (1) Polyunsaturated (2 or more)

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9
Q

Why are fatty acids with no double bonds between carbon atoms called saturated?

A

They form the maximum number of bonds with hydrogen atoms

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10
Q

Why are unsaturated fatty acids liquid at rt?

A

The presence of double bonds causes the molecule to kink/bend so it cannot pack so closely together. This is why they are described as oils (liquids)

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11
Q

What elements do phospholipids contain?

A

Carbon, hydrogen, oxygen, phosphorus

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12
Q

Why are phospholipids soluble in water?

A

The phosphate ions are negatively charged, making them polar and soluble in water (able to form H bonds with water)

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13
Q

What is the structure of a phospholipid?

A

Glycerol, two fatty acids, one phosphate group

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14
Q

What are the two parts to phospholipids?

A

Phosphate head- polar, hydrophilic

Fatty acid tails- non polar, hydrophobic

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15
Q

How do phospholipids behave when they interact with water?

A

1- They form a layer with phosphate heads in the water and fatty acid tails sticking out of the water
2- They form a bilayer, hydrophobic tails point towards the centre, protected from the water by the phosphate heads

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16
Q

Why do phospholipids play a key role in forming cell membranes?

A

By forming a bilayer, they are able to separate an aqueous environment from the aqueous cytosol within cells.

17
Q

Describe the structure of a sterol.

A

They have a four carbon ring structure with an OH group- have a dual hydrophobic/ hydrophilic nature

18
Q

What is the role of cholesterol?

A

It plays a role in the formation of cell membranes. It positions itself in between the phospholipids, adding to the stability of cell membranes and regulating their fluidity.

19
Q

Manufacture of cholesterol?

A

Body manufactures it in the liver/ intestines.

Steroid hormones/ bile are manufactured using cholesterol

20
Q

What are the roles of lipids?

A
  1. Membrane formation
  2. Hormone production
  3. Electrical insulation
  4. Cushioning to protect vital organs
  5. Thermal insulation
  6. Waterproofing
21
Q

What is the test to identify lipids?

A

Emulsion test- mix the sample with ethanol and then water, then shake
If a white emulsion forms on top, a lipid is present