ligands Flashcards

1
Q

What is the colour change when you react Cu2+ with NaOH?

A

Pale blue solution to blue gelatinous precipitate

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2
Q

What is the equation when you react Cu2+ with NaOH?

A

[Cu(H2O)6]2+ (aq) + 2OH- (aq) = [Cu(OH2)(H2O)4] (s) + 2H2O (l)

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3
Q

What is the colour change when you react Cu2+ with a small amount of NH3?

A

Pale blue solution to blue gelatinous precipitate

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4
Q

What is the equation when you react Cu2+ with a small amount of NH3?

A

[Cu(H2O)6]2+ (aq) + 2NH3 (aq) = [Cu(OH)2(H2O)4] (s) + 2NH4+ (aq)

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5
Q

What happens when you react Cu2+ with excess NH3?

A

It redissolves to form a deep blue solution containing [Cu(NH3)4(H2O)2]2+ (aq) ions

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6
Q

What is the colour change when you react Fe2+ with NaOH?

A

Pale gree solution to green precipitate

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7
Q

What is the equation when you react Fe2+ with NaOH?

A

[Fe(H2O)6]2+ (aq) + 2OH- (aq) = [Fe(OH)2(H2O)4] (s) + 2H2O (l)

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8
Q

What is the colour change when you react Fe2+ with NH3?

A

Pale green solution togreen precipitate

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9
Q

What happens when the Fe2+ solution is left standing in air?

A

It turns a rusty brown colour

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10
Q

What is the equation when you react Fe2+ with NH3?

A

[Fe(H2O)6]2+ (aq) + 2NH3 (aq) = [Fe(OH)2(H2O)4] (s) + 2NH4+ (aq)

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11
Q

What is the colour change when you react Fe3+ with NaOH?

A

Pale yellow solution to orange - brown precipitate

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12
Q

What is the equation when you react Fe3+ with NaOH?

A

[Fe(H2O)6]3+ (aq) + 3OH- (aq) = [Fe(OH)3(H2O)3] (s) + 3H2O (l)

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13
Q

What is the colour change when you react Fe3+ with NH3?

A

Pale yellow solution to orange - brown precipitate

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14
Q

What is the equation when you react Fe3+ with NH3?

A

[Fe(H2O)6]3+ (aq) + 3NH3 (aq) = [Fe(OH)3(H2O)3] (s) + 3NH4+ (aq)

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15
Q

What is the colour change when you react Mn2+ with NaOH?

A

Pale pink solution to pale brown precipitate

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16
Q

What is the equation when you react Mn2+ with NaOH?

A

[Mn(H2O)6]2+ (aq) + 2OH- (aq) = [Mn(OH)2(H2O)4] (s) + 2H2O (l)

17
Q

What is the colour change when you react Mn2+ with NH3?

A

Pale pink solution to pale brown precipitate

18
Q

What is the equation when you react Mn2+ with NH3?

A

[Mn(H2O)6]2+ (aq) + 2NH3 (aq) = [Mn(OH)2(H2O)4] (s) + 2NH4+ (aq)

19
Q

What happens if the precipitate in left standing in the air?

A

The precipitate oxidises and darkens

20
Q

What is the colour change when you react Cr3+ with a small amount of NaOH?

A

Violet solution to green precipitate

21
Q

What is the equation when you react Cr3+ with a small amount of NaOH?

A

[Cr(H2O)6]3+ (aq) + 3OH- (aq) = [Cr(OH)3(H2O)3] (s) + 3H2O (l)

22
Q

What is the colour change when you react Cr3+ with an excess of NaOH?

A

Green precipitate dissolves forming a dark green solution

23
Q

What is the equation when you react Cr3+ with an excess of NaOH?

A

[Cr(OH)3(H2O)3] (s) + 3OH- (aq) = [Cr(OH)6]3- (aq) + 3H2O (l)

24
Q

What is the colour change when you react Cr3+ with a small amount of NH3?

A

Violet solution to green precipitate

25
What is the equations when you react Cr3+ with a small amount of NH3?
[Cr(H2O)6]3+ (aq) + 3NH3 (aq) = [Cr(OH)3(H2O)3] (s) + 3NH4+ (aq)
26
What happens when you react Cr3+ with excess NH3?
The green precipitate redissolves to form a purple solution containing [Cr(NH3)6]3+ (aq) ions