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Chemistry - Organics > Level 3 Reactions > Flashcards

Level 3 Reactions Flashcards

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1
Q

Keytone –> secondary alcohol

A

NaBH4 / LiAH4

Reduction

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2
Q

Keytone + NaBH4

A

Secondary Alcohol

Reduction

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3
Q

Secondary Alcohol –> Keytone

A

Dichromate

Oxidation

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4
Q

Secondary Alcohol + Dicromate

A

Keytone

Oxidation

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5
Q

Primary Alcohol —> Ester

A

Alcohol + Carboxylic acid + concentrated H2SO4 (catalyst)

condensation

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6
Q

Primary Alcohol + Carboxylic acid + concentrated H2SO4 (catalyst)

A

Ester

Condensation

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7
Q

Primary Alcohol + controlled dicromate

A

Aldehyde

Oxidation

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8
Q

Primary Alcohol –> Aldehyde

A

controlled dicromate

Oxidation

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9
Q

Aldehyde —> Primary Alcohol

A

NaBH4 / LiAH4

Reduction

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10
Q

Aldehyde + [AgNH3]+ and heat

A

Silver Mirror Formed

Tollen’s Reagent

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11
Q

Tollen’s Reagent

A

Aldehyde + [AgNH3]+ and heat
Silver Mirror Formed
Ag undergoes oxidation while the aldehyde undergoes reduction

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12
Q

Fehling Reagent

A

Aldehyde + copper complex ion and heat
Blue Cu2+ to Cu+, a red/orange precipitate
Ag undergoes oxidation while the aldehyde undergoes reduction

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13
Q

Aldehyde + NaBH4 / LiAH4

A

Primary Alcohol

Reduction

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14
Q

Aldehyde –> Carboxylic acid

A

Dicromate

Oxidation

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15
Q

Aldehyde + Dicromate

A

Carboxylic acid

Oxidation

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16
Q

Primary Alcohol —> Carboxylic acid

A

Dicromate / Permanganate

17
Q

Primary alcohol + Dicromate / Permanganate

A

Carboxylic acid

18
Q

Carboxylic acid —> ester

A

+ alcohol + H2SO4 concentrated

condensation

19
Q

Ester —> Carboxylic acid

A

+ H20
Hydrolyisis under acidic conditions
(HCl in aq)

20
Q

Ester + HCl (aq)

A

Carboxylic acid

Hydrolyisis under acidic conditions

21
Q

Ester —> Carboxylate ion

A

+ H20
Hydrolyisis under basic conditions
(NaOH in aq)

22
Q

Ester + NaOH (aq)

A

Carboxylate ion

23
Q

Ester —> Amide

A

NH3 (alc) or primary amine and heat

24
Q

Ester + NH3 (alc) or primary amine and heat

A

Amide

25
Q

Carboxylic acid —> Amide

A

NH3 (alc) or primary amine and heat

Substitution

26
Q

Carboxylic acid + NH3 (alc) or primary amine and heat

A

Amide

Substitution

27
Q

Amide —> Carboxylic acid

A

+H20
Under acidic conditions
(HCl in aq)

28
Q

Amide + HCl(aq)

A

Carboxylic acid

Hydrolysis Under acidic conditions

29
Q

Amide —> Carboxylate

A

+H20
basic conditions
(NaOH in aq)

30
Q

Amide + NaOH (aq)

A

Carboxylate

31
Q

Acid Chloride + H20

A

Carboxylic acid

32
Q

Acid Chloride —> Carboxylic acid

A

+H20

Substitution

33
Q

Carboxylic acid + SOCl2

A

Acid Chloride

Substitution

34
Q

Carboxylic acid —> Acid chloride

A

SoCl2

Substitution

35
Q

Acid Chloride —> Carboxylate

A

NaOH (aq)

Chemistry - Organics (2 decks)

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