lesson 5 & 6 Flashcards

1
Q

what is energy?

A

the capacity to do work or to produce heat.

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2
Q

law of conservation of energy.

A

energy can be converted from one form to another but it can’t be created or destroyed.

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3
Q

what is potential energy?

A

energy because of the position or composition.

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4
Q

kinetic energy

A

energy because of the motion of the object.

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5
Q

heat?

A

transfer of energy due to temperature differences.

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6
Q

work?

A

force acting over a distance.

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7
Q

energy is a state function, what doe that mean?

A

only the present matters.

the past or future of system doesn’t matter.

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8
Q

whats the difference between heat and temperature.

A

temperature is the random motion of particles. while heat is the difference in temperature.

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9
Q

what is a system?

A

the part of the universe that we focus on

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10
Q

what is surroundings?

A

everything in the universe.

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11
Q

what are endothermic reaction?

A

a reaction that absorbs energy from surroundings,

energy from surroundings to system

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12
Q

what is an exothermic reaction?

A

a reaction that releases energy into the surrounding.

energy from system to surroundings

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13
Q

thermodynamics?

A

the study of energy and its conservation.

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14
Q

what is the first law of thermodynamics.

A

law of conversion of energy.

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15
Q

law of conversion of energy states …

A

the energy of the universe is constant.

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16
Q

internal energy?

A

sum of potential energy of all the “particles” in a system.

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17
Q

what affects internal energy

A

flow of work, heat, or both.

18
Q

change in energy equals?

A

change in E = q + w

19
Q

internal energy consists of

A

is a vector. so it consists of a number and sign.

20
Q

when is q positive and when is it negative.

A

positive: endothermic
negative: exothermic.

21
Q

when is work negative and when is it positive?

A

negative: when the system does the work
positive: when the surrounding does the work.

22
Q

how did we reach to the equation that W = P * (change in V)

A

W = F (change in distance)
F = P * A
if we substitute F with its equation we get W = P * A * (change in h)
(change in V) = final volume - initial volume = A * (change in h)
substituting with that we ger. W = P * (change in V)

23
Q

1 L·atm = ? J

A

101.3

24
Q

enthalpy

A

the combination of internal energy and work done by/on system
H = E + PV

25
Q

when is a reaction endothermic and when is it exothermic?

A
endothermic = change in enthalpy is positive
exothermic = change in enthalpy is negative
26
Q

Calorimetry

A

Science of measuring heat

27
Q

Specific heat capacity:

A

The energy required to raise the temperature of one gram of a substance by one degree Celsius.

28
Q

Molar heat capacity:

A

The energy required to raise the temperature of one mole of a substance by one degree Celsius

29
Q

Types of Calorimeter

A

Constant P Calorimeter (Coffee Cup)

Constant V Calorimeter (Bomb Calorimeter)

30
Q

what is a coffee cup calorimeter made of?

A

Two Styrofoam Cups

31
Q

Constant-pressure calorimetry is used ……

A

pressure remains constant during the process. Constant-pressure calorimetry is used in determining the changes in enthalpy (heats of reactions) for reactions occurring in solution.

32
Q

Energy released (heat) = ?

A

Energy released (heat) = s × m × ΔT

33
Q

when is bomb calorimeter used

A

When the volume remains constant during a reaction, (in a

closed container), a bomb calorimeter is used.

34
Q

how do we measure the energy released by reaction in a bomb calorimeter?

A

The energy released by the reaction = change in T x heat capacity of Calorimeter

35
Q

Bomb Calorimeter made of

A

thermometer, steel bomb, reactants in the sample cup, water, insulation container.

36
Q

what is Hess’s Law?

A

In going from a particular set of reactants to a particular set of products, the change in enthalpy is the same whether the reaction takes place in one step or in a series of steps

37
Q

Characteristics of Enthalpy Changes

A

If a reaction is reversed, the sign of ΔH is also reversed.

The magnitude of ΔH is directly proportional to the quantities of reactants and products in a reaction.

38
Q

Standard Enthalpy of Formation

A

Change in enthalpy that accompanies the formation of one mole of a compound from its elements with all substances in their standard states

39
Q

Conventional Definitions of the Standard States For a Compound

A

For a gas, pressure is exactly 1 atm.
For a solution, the concentration is exactly 1 M.
Pure substance in the condensed state the standard state is the pure liquid or solid)

40
Q

Conventional Definitions of the Standard States For an Element

A

The form [N2 (g), K(s)] in which it exists at 1 atm and 25°C