lecture Flashcards
what is condensation
gas to liquid
what is fusion/ melting
solid to liquid
what is freezing/ crystallization
liquid to solid
what is vaporization
liquid to gas
what is sublimation
solid to gas
what is deposition
gas to solid
what is the specific heat of liquid water
1 calorie/ gram celcius
Heat capacity formula
q=mcAT
Kinetic molecular Theory of gases
- particles have negligible Volume.
- There e are no intermolecular attractions or repulsions.
- Molecules ar ein continuous and random motion.
- Collisions are elastic. Conservation of Kinetic Energy is observed.
- The average kinetic energy of gas particles is proportional to the absolute temperature.
Daltons Law of partial pressures
In a mixture of gases, total pressure equals the sum of the pressures for each individual gas.
PA= XA Ptotal
Boyle’s Law
at constant temperature, the volume of a gas is inversely proportional to its pressure
P1 V1= P2 V2
Charles’s Law
at constant pressure, a gas volume is directly proportional to its temperature.
(V1/T1)= (V2/T2)
Avogadros’ Law
The volume of a gas is directly proportional to the number of moles of the gas in.
(V1/n1)= (V2/n2)
whats Standard Temperature and Pressure STP
1 atm
273 K
22.4L
R value is?
8.314 atm or 0.0831 J
Molarity (M)
Concentration
M= Moles of solute/ Liters of solutions
molality (m)
used for colligative properties
m= Moles of solute/ Kg of solvents
Dilution Formula
M1V1=M2V2
Arrhenius Acid
Proton donor (H+)
Arrhenius Base
Hydroxide ion donor (OH-)
Bronsted-Lowry Acid
proton donor
Bronsted-Lowry Base
Proton aceptor
Lewis acid
electron pair acceptor
lewis base
electron pair donor
Autoionization of water
Kw= [H+][OH-]= 1 x 10^ -14
Acid Dissociation constant
Ka= [A-][H3O+]/ [HA]
Base Dissociation Constant
Kb= [HB+][OH-]/[B]
Equivalence Point equation
VA NA= VB NB
Normality Formula
N=Mx (equivalents/mol)
Henderson-Hasselbalch Equation
PH= Pka + log [Conjugate base/ weak acid]
POH= Pkb + log [Conjugate acid/weak base]
Reduction
Gain of electrons
Oxidation
Loose of electrons
Reducing agentCaO
Reduces something; becomes oxidized
Oxidation agent
Oxidizes something; becomes reduced
what are elastic collisions
elastic collision are those in which the colliding particle do not stick together and translational kinetic energy is not dissipated, such as those in an ideal gas.
Inelastic collisions occur between molecules in
real gases & fusions reactions.
according to the solubility rules which compounds are always soluble?
nitrates, alkali metals & ammonium
Solubility rules
1) All metal oxides are insoluble with the exception of CaO, SrO, BaO and alkali metal oxides.
2) Hydroxides are insoluble, with the exception of Ca+2, Sr+2, Ba+2 and the alkali metal hydroxides.
3) All sulfate salts are soluble exceptCa+2, Sr+2, Ba+2