Lecture 4 Flashcards
Why is the ocean salty
- the ocean is salty because of dissolved chemicals eroded from the Earth’s crust and washed into the seas
- there are also ejections from volcanos, particles being swept to the ocean by winds, and materials dissolved from sediment deposited on the ocean floor
What is the biogeochemical cycle consist of
- weathering and erosion of continental rocks
- > these are then transported to the oceans
- > this is all part of a large, slow cycle
What is the definition of biogeochemical cycle
-pathways by which a chemical susbtrate moves through the biotic(biosphere) and abiotic(litrosphere, atmosphere, hydrosphere)
Do the compounds or solids dissolved in the ocean remain in the ocean
- no
- > they cycle into and out of the ocean by various processes
- > in by processes such as river discharge, volcanic eruption or hydrothermal activity
- > out by processes such as ocean precipitation and biological processes
Is the ocean in steady-state
- yes we assume the oceans are in steady state and the average amounts of various elements remain constant
- > quantity in= quantity out
What is the residence time
- the average length of time that a substance resides in the ocean
- > long residence time leads to higher concentrations of the dissolved substance
-residence time is essentially the time taken to replace all of the given substance in the ocean with new material of that substance from other sources
- R=M/I=M/O
- > no units because kilograms cancel out
What is the definition of salinity
- it is the total amount of dissolved material in grams in 1 kg of seawater
- > it is dimensionless and has no units
- salinity of seawater is about 3.5%
- > it is about 220 times saltier than freshwater
What is salinity expressed as
- it is expressed as: grams of dissolved salts/kilogram of seawater
- > can be expressed in parts per thousant
How do chemicals in seawater appear as
- they usually appear as compound ions rather than actual raw elements
- > so phosphate for example
-chemicals in seawater include most elements, a variety of radionuclides and numerous organic compounds
- they are designated as major, minor or trace
- > this just reflects their concentrations
How are dissolved chemicals in the ocean measured
- in parts per million
- > eg; 1 teaspoonfull in 5000 litres of water
- > parts per million is used for compounds that are designated as major
- in parts per billion
- > eg; 1 teaspoonfull in 5,000,000 litres of water
- > parts per billion is usually for compounds that are designated as trace or minor
What are the six major consitituents of seawater
- chlorine
- sodium
- sulfate
- magnesium
- calcium
- potassium
-these six make up together 99.28% of all salts in seawater
What are the minor constituents in seawater
- bromine
- carbon
- strontium
- boron
- silicon
- fluorine
- concentrations range from 1 to 100 parts per million
-note some are very important for biological processes
What is the major process to remove major constituents
- it is through the precipitation of salt deposits
- > which mainly occur in marginal seas with high evaporation
- the residence times for major constituents are very long
- > the associated river/erosion inputs are very slow
- > thus the concentrations of these ions vary little to little from time to place
- the concentrations of minor and trace elements are so low
- > the sources are also often localized
- > so the concentrations of trace elements can vary significantly in different parts of the ocean
Can minor and trace constituents change in distribution in a location over time
- yes
- >not something you would see in a major constituent
Describe the differences in freshwater from seawater
- since seawater is 96.5% water
- > many of its physical properties are shared with that of pure water
- > except that of freezing point, boiling point, pH and density
- the dissolved substances in sea water decrease the freezing point of sea water in comparison to pure water
- > while at the same time increase the boiling point of seawater
-seawater is more alkaline than pure water and has a higher pH
- seawater is slightly more dense than pure water
- > this is due to increasing salinity